Characteristic responses of an atmospheric pressure DC micro-plasma detector for gas chromatography to organic functional groups

Yu Mao Fu, Shih Chi Chu, Chia-Jung Lu

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A gas chromatographic detector using direct current micro-plasma discharged a distance of less than 50 μm under helium at atmospheric pressure is described. The micro-plasma device was assembled on glass substrates; the volume of the plasma region was only 0.58 nL. Very low power consumption (15 mW) and only carrier helium flow were needed to maintain micro-plasma stability. Organic compounds with various functional groups were chromatographically separated and fed into the micro-plasma. Fluctuations in plasma current were detected as the sample passed through the micro-plasma. All non-halogen organics showed positive peaks, while simple alkyl halides showed negative peaks. Compounds with both aromatic and halogen groups exhibited hybrid peak shapes, consisting of both positive and negative peaks. The detection limits (3σ) ranged from 24.5 pg for m-xylene to 756 pg for 1,2-dichloroethane, depending on differences in ionization and electron-capture efficiency.

Original languageEnglish
Pages (from-to)7-12
Number of pages6
JournalMicrochemical Journal
Volume89
Issue number1
DOIs
Publication statusPublished - 2008 Jun 1

Fingerprint

Gas chromatography
Functional groups
Atmospheric pressure
Detectors
Plasmas
Helium
Plasma devices
Plasma stability
Halogens
Organic compounds
Ionization
Electric power utilization
Gases
Glass
Electrons
Substrates

Keywords

  • Gas chromatograph
  • Helium discharge detector
  • Micro-plasma

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy

Cite this

Characteristic responses of an atmospheric pressure DC micro-plasma detector for gas chromatography to organic functional groups. / Fu, Yu Mao; Chu, Shih Chi; Lu, Chia-Jung.

In: Microchemical Journal, Vol. 89, No. 1, 01.06.2008, p. 7-12.

Research output: Contribution to journalArticle

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