catena-Poly[[tetraaquanickel(II)]- 3-benzene-1,3,5- tricarboxylato-3′:1:2-4 O 1:O 3,O 3′:O 5-[tetraaquanickel(II)]- 2-benzene- 1,3,5-tricarboxylato-2:32 O 1:O 3- [tetraaquanickel(II)]]

Shih Chen Hsu; Pei Hsuan Chiang; Chih Hsien Chang; Chia Her Lin

doi:10.1107/S1600536809016729

catena-Poly[[tetraaquanickel(II)]- ₃-benzene-1,3,5- tricarboxylato-3′:1:2-⁴ O ¹:O ³,O ^3′:O ⁵-[tetraaquanickel(II)]- ₂-benzene- 1,3,5-tricarboxylato-2:3² O ¹:O ³- [tetraaquanickel(II)]]

Shih Chen Hsu, Pei Hsuan Chiang, Chih Hsien Chang, Chia Her Lin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The microwave solvothermal reaction of nickel nitrate with trimesic acid provided the title compound, [Ni₃(BTC)₂(H₂O) ₁₂]_n(BTC = benzene-1,3,5-tricarboxyl-ate anion, C ₉H₃O₆), which is a metal coordination polymer composed of one-dimensional zigzag chains. The crystal under investigation was ramecically twinned with an approximate twin domain ratio of 1:1. In the asymmetric unit, there are two types of Ni atoms. One of the NiO₆ groups (2 symmetry) is coordinated to only one carboxyl-ate group and thus terminal, the other is bridging, forming the coordination polymer. The extended chains are connected by the organic BTC anions via ₂-linkages. O - H⋯O hydrogen bonds and π-π inter-actions between the chains [centroid-centroid distance 3.58 (1) Å] induce the complex to mimic a three-dimensional structure.

Original language	English
Pages (from-to)	m625-m626
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	6
DOIs	https://doi.org/10.1107/S1600536809016729
Publication status	Published - 2009
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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Hsu, S. C., Chiang, P. H., Chang, C. H., & Lin, C. H. (2009). catena-Poly[[tetraaquanickel(II)]- ₃-benzene-1,3,5- tricarboxylato-3′:1:2-⁴ O ¹:O ³,O ^3′:O ⁵-[tetraaquanickel(II)]- ₂-benzene- 1,3,5-tricarboxylato-2:3² O ¹:O ³- [tetraaquanickel(II)]]. Acta Crystallographica Section E: Structure Reports Online, 65(6), m625-m626. https://doi.org/10.1107/S1600536809016729

catena-Poly[[tetraaquanickel(II)]- ₃-benzene-1,3,5- tricarboxylato-3′:1:2-⁴ O ¹:O ³,O ^3′:O ⁵-[tetraaquanickel(II)]- ₂-benzene- 1,3,5-tricarboxylato-2:3² O ¹:O ³- [tetraaquanickel(II)]]. / Hsu, Shih Chen; Chiang, Pei Hsuan; Chang, Chih Hsien et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 6, 2009, p. m625-m626.

Research output: Contribution to journal › Article › peer-review

Hsu, SC, Chiang, PH, Chang, CH & Lin, CH 2009, 'catena-Poly[[tetraaquanickel(II)]- ₃-benzene-1,3,5- tricarboxylato-3′:1:2-⁴ O ¹:O ³,O ^3′:O ⁵-[tetraaquanickel(II)]- ₂-benzene- 1,3,5-tricarboxylato-2:3² O ¹:O ³- [tetraaquanickel(II)]]', Acta Crystallographica Section E: Structure Reports Online, vol. 65, no. 6, pp. m625-m626. https://doi.org/10.1107/S1600536809016729

@article{bedcdc4788ef4467a49b4cc8e4bdeeb2,

title = "catena-Poly[[tetraaquanickel(II)]- 3-benzene-1,3,5- tricarboxylato-3′:1:2-4 O 1:O 3,O 3′:O 5-[tetraaquanickel(II)]- 2-benzene- 1,3,5-tricarboxylato-2:32 O 1:O 3- [tetraaquanickel(II)]]",

abstract = "The microwave solvothermal reaction of nickel nitrate with trimesic acid provided the title compound, [Ni3(BTC)2(H2O) 12]n(BTC = benzene-1,3,5-tricarboxyl-ate anion, C 9H3O6), which is a metal coordination polymer composed of one-dimensional zigzag chains. The crystal under investigation was ramecically twinned with an approximate twin domain ratio of 1:1. In the asymmetric unit, there are two types of Ni atoms. One of the NiO6 groups (2 symmetry) is coordinated to only one carboxyl-ate group and thus terminal, the other is bridging, forming the coordination polymer. The extended chains are connected by the organic BTC anions via 2-linkages. O - H⋯O hydrogen bonds and π-π inter-actions between the chains [centroid-centroid distance 3.58 (1) {\AA}] induce the complex to mimic a three-dimensional structure.",

author = "Hsu, {Shih Chen} and Chiang, {Pei Hsuan} and Chang, {Chih Hsien} and Lin, {Chia Her}",

year = "2009",

doi = "10.1107/S1600536809016729",

language = "English",

volume = "65",

pages = "m625--m626",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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AU - Hsu, Shih Chen

AU - Chiang, Pei Hsuan

AU - Chang, Chih Hsien

AU - Lin, Chia Her

PY - 2009

Y1 - 2009

N2 - The microwave solvothermal reaction of nickel nitrate with trimesic acid provided the title compound, [Ni3(BTC)2(H2O) 12]n(BTC = benzene-1,3,5-tricarboxyl-ate anion, C 9H3O6), which is a metal coordination polymer composed of one-dimensional zigzag chains. The crystal under investigation was ramecically twinned with an approximate twin domain ratio of 1:1. In the asymmetric unit, there are two types of Ni atoms. One of the NiO6 groups (2 symmetry) is coordinated to only one carboxyl-ate group and thus terminal, the other is bridging, forming the coordination polymer. The extended chains are connected by the organic BTC anions via 2-linkages. O - H⋯O hydrogen bonds and π-π inter-actions between the chains [centroid-centroid distance 3.58 (1) Å] induce the complex to mimic a three-dimensional structure.

AB - The microwave solvothermal reaction of nickel nitrate with trimesic acid provided the title compound, [Ni3(BTC)2(H2O) 12]n(BTC = benzene-1,3,5-tricarboxyl-ate anion, C 9H3O6), which is a metal coordination polymer composed of one-dimensional zigzag chains. The crystal under investigation was ramecically twinned with an approximate twin domain ratio of 1:1. In the asymmetric unit, there are two types of Ni atoms. One of the NiO6 groups (2 symmetry) is coordinated to only one carboxyl-ate group and thus terminal, the other is bridging, forming the coordination polymer. The extended chains are connected by the organic BTC anions via 2-linkages. O - H⋯O hydrogen bonds and π-π inter-actions between the chains [centroid-centroid distance 3.58 (1) Å] induce the complex to mimic a three-dimensional structure.

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catena-Poly[[tetraaquanickel(II)]- ₃-benzene-1,3,5- tricarboxylato-3′:1:2-⁴ O ¹:O ³,O ^3′:O ⁵-[tetraaquanickel(II)]- ₂-benzene- 1,3,5-tricarboxylato-2:3² O ¹:O ³- [tetraaquanickel(II)]]

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