Catena-Poly[[diaqua-magnesium(II)]-bis-(μ-5-ammonio-isophthalato- κ2 O 1:O 3)]

Cheng You Wu; Chia Her Lin

doi:10.1107/S1600536810040250

Catena-Poly[[diaqua-magnesium(II)]-bis-(μ-5-ammonio-isophthalato- κ² O ¹:O ³)]

Cheng You Wu, Chia Her Lin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title compound, [Mg(C₈H₆NO₄) ₂(H₂O)₂]_n, the Mg^II ion lies on a twofold roatation axis and is coordinated in a slightly distorted octa-hedral environment. Pairs of bridging ammonium-isophthalate ligands connect symmetry-related Mg^II ions, forming chains along [010]. In the crystal, inter-molecular O - H⋯O and N - H⋯O hydrogen bonds link these chains into a three-dimensional network. The centroids of pairs of symmetry-related benzene rings within a chain are separated by 3.5707 (12) Å.

Original language	English
Pages (from-to)	m1437
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	11
DOIs	https://doi.org/10.1107/S1600536810040250
Publication status	Published - 2010 Nov
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Catena-Poly[[diaqua-magnesium(II)]-bis-(μ-5-ammonio-isophthalato- κ2 O 1:O 3)]",

abstract = "In the title compound, [Mg(C8H6NO4) 2(H2O)2]n, the MgII ion lies on a twofold roatation axis and is coordinated in a slightly distorted octa-hedral environment. Pairs of bridging ammonium-isophthalate ligands connect symmetry-related MgII ions, forming chains along [010]. In the crystal, inter-molecular O - H⋯O and N - H⋯O hydrogen bonds link these chains into a three-dimensional network. The centroids of pairs of symmetry-related benzene rings within a chain are separated by 3.5707 (12) {\AA}.",

author = "Wu, {Cheng You} and Lin, {Chia Her}",

year = "2010",

month = nov,

doi = "10.1107/S1600536810040250",

language = "English",

volume = "66",

pages = "m1437",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "11",

}

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T1 - Catena-Poly[[diaqua-magnesium(II)]-bis-(μ-5-ammonio-isophthalato- κ2 O 1:O 3)]

AU - Wu, Cheng You

AU - Lin, Chia Her

PY - 2010/11

Y1 - 2010/11

N2 - In the title compound, [Mg(C8H6NO4) 2(H2O)2]n, the MgII ion lies on a twofold roatation axis and is coordinated in a slightly distorted octa-hedral environment. Pairs of bridging ammonium-isophthalate ligands connect symmetry-related MgII ions, forming chains along [010]. In the crystal, inter-molecular O - H⋯O and N - H⋯O hydrogen bonds link these chains into a three-dimensional network. The centroids of pairs of symmetry-related benzene rings within a chain are separated by 3.5707 (12) Å.

AB - In the title compound, [Mg(C8H6NO4) 2(H2O)2]n, the MgII ion lies on a twofold roatation axis and is coordinated in a slightly distorted octa-hedral environment. Pairs of bridging ammonium-isophthalate ligands connect symmetry-related MgII ions, forming chains along [010]. In the crystal, inter-molecular O - H⋯O and N - H⋯O hydrogen bonds link these chains into a three-dimensional network. The centroids of pairs of symmetry-related benzene rings within a chain are separated by 3.5707 (12) Å.

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Catena-Poly[[diaqua-magnesium(II)]-bis-(μ-5-ammonio-isophthalato- κ² O ¹:O ³)]

Abstract

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