Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility

Ling I. Hung; Hsiang Yi Yi; Yu Chieh Shih; Chia Her Lin; Sue Lein Wang

doi:10.1039/c8cc09289c

Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility

Ling I. Hung, Hsiang Yi Yi, Yu Chieh Shih, Chia Her Lin, Sue Lein Wang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

For the first time, functional carboxylic acid (-COOH) groups protruding on both sides of zincophosphate sheets are prepared, leading to a unique surface-active lamellar material characterized by modifiable wettability via a facile mechanochemical reaction. The interior -COOH groups lead to high thermal stability unusual to hybrid-layer structures and undergo the intriguingly reversible nano-morphological transformation never unveiled in metal oxysalts before.

Original language	English
Pages (from-to)	2429-2432
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	17
DOIs	https://doi.org/10.1039/c8cc09289c
Publication status	Published - 2019
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c8cc09289c

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abstract = "For the first time, functional carboxylic acid (-COOH) groups protruding on both sides of zincophosphate sheets are prepared, leading to a unique surface-active lamellar material characterized by modifiable wettability via a facile mechanochemical reaction. The interior -COOH groups lead to high thermal stability unusual to hybrid-layer structures and undergo the intriguingly reversible nano-morphological transformation never unveiled in metal oxysalts before.",

author = "Hung, {Ling I.} and Yi, {Hsiang Yi} and Shih, {Yu Chieh} and Lin, {Chia Her} and Wang, {Sue Lein}",

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AU - Hung, Ling I.

AU - Yi, Hsiang Yi

AU - Shih, Yu Chieh

AU - Lin, Chia Her

AU - Wang, Sue Lein

PY - 2019

Y1 - 2019

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AB - For the first time, functional carboxylic acid (-COOH) groups protruding on both sides of zincophosphate sheets are prepared, leading to a unique surface-active lamellar material characterized by modifiable wettability via a facile mechanochemical reaction. The interior -COOH groups lead to high thermal stability unusual to hybrid-layer structures and undergo the intriguingly reversible nano-morphological transformation never unveiled in metal oxysalts before.

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JO - Chemical Communications

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Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility

Abstract

ASJC Scopus subject areas

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