Carbonization and oxidation of metal-organic frameworks based on 1,4-naphthalene dicarboxylates

Jiun Jen Chen, Ya Ting Chen, Duraisamy Senthil Raja, Yu Hao Kang, Pen Chang Tseng, Chia Her Lin

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

Three new isostructural metal-organic frameworks (MOFs), [V(OH)(NDC)] (1), [Cr(OH)(NDC)] (2), and [Ga(OH)(NDC)] (3) have been synthesized hydrothermally using 1,4-naphthalene dicarboxylate (NDC) as the linker. These MOFs (1, 2 and 3) have been used as a template for the synthesis of metal-oxide-inserted nanoporous carbon materials. The newly synthesized MOFs and the resulting porous carbon hybrid functional materials have been characterized using powder x-ray diffraction, scanning electron microscopy, transmission electron microscopy, and energy dispersive x-ray spectroscopic analysis. Results show that compounds 2 and 3 form their respective metal oxide nanoparticles on the surface of the carbon materials during carbonization at 800 °C. The gas sorption properties of the new MOFs and their corresponding carbon frameworks have been reported.

Original languageEnglish
Article number054203
JournalScience and Technology of Advanced Materials
Volume16
Issue number5
DOIs
Publication statusPublished - 2015 Oct 6
Externally publishedYes

Keywords

  • metal oxide nanoparticle
  • metal-organic frameworks
  • nanoporous carbon

ASJC Scopus subject areas

  • General Materials Science

Fingerprint

Dive into the research topics of 'Carbonization and oxidation of metal-organic frameworks based on 1,4-naphthalene dicarboxylates'. Together they form a unique fingerprint.

Cite this