Bis(4,4′-methyl-enedicyclo-hexyl-aminium)-μ-benzene-1, 4-dicarboxyl-ato-bis-[tri-chlorido-zinc(II)] tetra-hydrate

Chia Her Lin; Chen Yen Hsu; Chun Wei Yeh; Chi Phi Wu; Jhy Der Chen

doi:10.1107/S1600536808033011

Bis(4,4′-methyl-enedicyclo-hexyl-aminium)-μ-benzene-1, 4-dicarboxyl-ato-bis-[tri-chlorido-zinc(II)] tetra-hydrate

Chia Her Lin^*
, Chen Yen Hsu
, Chun Wei Yeh
, Chi Phi Wu
, Jhy Der Chen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound, (C13H28N2)2[Zn2(C8H4O4)Cl6]·4H2O, was prepared by the reaction of ZnCl2·6H2O, benzene-1,4-dicarboxylic acid and 4,4′-diamino-dicyclo-hexyl-methane in methanol. The [Zn2Cl6(C8H4O4)] ^4- anions lie on centres of inversion and comprise two ZnCl3 groups bridged by benzene-1,4-dicarboxyl-ate. In addition to N - H⋯Cl and N - H⋯O hydrogen bonds between the cations and anions, solvent water mol-ecules form O - H⋯O and O - H⋯Cl hydrogen bonds to give a three-dimensional network.

Original language	English
Pages (from-to)	m1412
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	11
DOIs	https://doi.org/10.1107/S1600536808033011
Publication status	Published - 2008
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{2dc635642be3424593b1072c109debbe,

title = "Bis(4,4′-methyl-enedicyclo-hexyl-aminium)-μ-benzene-1, 4-dicarboxyl-ato-bis-[tri-chlorido-zinc(II)] tetra-hydrate",

abstract = "The title compound, (C13H28N2)2[Zn2(C8H4O4)Cl6]·4H2O, was prepared by the reaction of ZnCl2·6H2O, benzene-1,4-dicarboxylic acid and 4,4′-diamino-dicyclo-hexyl-methane in methanol. The [Zn2Cl6(C8H4O4)] 4- anions lie on centres of inversion and comprise two ZnCl3 groups bridged by benzene-1,4-dicarboxyl-ate. In addition to N - H⋯Cl and N - H⋯O hydrogen bonds between the cations and anions, solvent water mol-ecules form O - H⋯O and O - H⋯Cl hydrogen bonds to give a three-dimensional network.",

author = "Lin, \{Chia Her\} and Hsu, \{Chen Yen\} and Yeh, \{Chun Wei\} and Wu, \{Chi Phi\} and Chen, \{Jhy Der\}",

year = "2008",

doi = "10.1107/S1600536808033011",

language = "English",

volume = "64",

pages = "m1412",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - Bis(4,4′-methyl-enedicyclo-hexyl-aminium)-μ-benzene-1, 4-dicarboxyl-ato-bis-[tri-chlorido-zinc(II)] tetra-hydrate

AU - Lin, Chia Her

AU - Hsu, Chen Yen

AU - Yeh, Chun Wei

AU - Wu, Chi Phi

AU - Chen, Jhy Der

PY - 2008

Y1 - 2008

N2 - The title compound, (C13H28N2)2[Zn2(C8H4O4)Cl6]·4H2O, was prepared by the reaction of ZnCl2·6H2O, benzene-1,4-dicarboxylic acid and 4,4′-diamino-dicyclo-hexyl-methane in methanol. The [Zn2Cl6(C8H4O4)] 4- anions lie on centres of inversion and comprise two ZnCl3 groups bridged by benzene-1,4-dicarboxyl-ate. In addition to N - H⋯Cl and N - H⋯O hydrogen bonds between the cations and anions, solvent water mol-ecules form O - H⋯O and O - H⋯Cl hydrogen bonds to give a three-dimensional network.

AB - The title compound, (C13H28N2)2[Zn2(C8H4O4)Cl6]·4H2O, was prepared by the reaction of ZnCl2·6H2O, benzene-1,4-dicarboxylic acid and 4,4′-diamino-dicyclo-hexyl-methane in methanol. The [Zn2Cl6(C8H4O4)] 4- anions lie on centres of inversion and comprise two ZnCl3 groups bridged by benzene-1,4-dicarboxyl-ate. In addition to N - H⋯Cl and N - H⋯O hydrogen bonds between the cations and anions, solvent water mol-ecules form O - H⋯O and O - H⋯Cl hydrogen bonds to give a three-dimensional network.

UR - https://www.scopus.com/pages/publications/55749113191

UR - https://www.scopus.com/pages/publications/55749113191#tab=citedBy

U2 - 10.1107/S1600536808033011

DO - 10.1107/S1600536808033011

M3 - Article

AN - SCOPUS:55749113191

SN - 1600-5368

VL - 64

SP - m1412

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Bis(4,4′-methyl-enedicyclo-hexyl-aminium)-μ-benzene-1, 4-dicarboxyl-ato-bis-[tri-chlorido-zinc(II)] tetra-hydrate

Abstract

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