TY - JOUR
T1 - Bis(4,4′-methyl-enedicyclo-hexyl-aminium)-μ-benzene-1, 4-dicarboxyl-ato-bis-[tri-chlorido-zinc(II)] tetra-hydrate
AU - Lin, Chia Her
AU - Hsu, Chen Yen
AU - Yeh, Chun Wei
AU - Wu, Chi Phi
AU - Chen, Jhy Der
PY - 2008
Y1 - 2008
N2 - The title compound, (C13H28N2)2[Zn2(C8H4O4)Cl6]·4H2O, was prepared by the reaction of ZnCl2·6H2O, benzene-1,4-dicarboxylic acid and 4,4′-diamino-dicyclo-hexyl-methane in methanol. The [Zn2Cl6(C8H4O4)] 4- anions lie on centres of inversion and comprise two ZnCl3 groups bridged by benzene-1,4-dicarboxyl-ate. In addition to N - H⋯Cl and N - H⋯O hydrogen bonds between the cations and anions, solvent water mol-ecules form O - H⋯O and O - H⋯Cl hydrogen bonds to give a three-dimensional network.
AB - The title compound, (C13H28N2)2[Zn2(C8H4O4)Cl6]·4H2O, was prepared by the reaction of ZnCl2·6H2O, benzene-1,4-dicarboxylic acid and 4,4′-diamino-dicyclo-hexyl-methane in methanol. The [Zn2Cl6(C8H4O4)] 4- anions lie on centres of inversion and comprise two ZnCl3 groups bridged by benzene-1,4-dicarboxyl-ate. In addition to N - H⋯Cl and N - H⋯O hydrogen bonds between the cations and anions, solvent water mol-ecules form O - H⋯O and O - H⋯Cl hydrogen bonds to give a three-dimensional network.
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U2 - 10.1107/S1600536808033011
DO - 10.1107/S1600536808033011
M3 - Article
AN - SCOPUS:55749113191
SN - 1600-5368
VL - 64
SP - m1412
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 11
ER -