Bis[2-(pyrimidin-2-ylamino)pyrimidin-ium] hexa-molybdate

Chun Wei Yeh; Chia Her Lin; Jhy Der Chen

doi:10.1107/S1600536807062897

Bis[2-(pyrimidin-2-ylamino)pyrimidin-ium] hexa-molybdate

Chun Wei Yeh
, Chia Her Lin^*
, Jhy Der Chen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound, (C8H8N5)2[Mo6O19], was prepared by reaction of Mo(CO)6 and dipyrimidylamine in refluxing toluene. The hexa-nuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intra-molecular N - H⋯N hydrogen bond and the cations are linked through self-complementary pairs of N - H⋯N hydrogen bonds into dimers across centres of inversion. The cations and anions are inter-linked through C - H⋯O contacts.

Original language	English
Pages (from-to)	m41
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	1
DOIs	https://doi.org/10.1107/S1600536807062897
Publication status	Published - 2008
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Bis[2-(pyrimidin-2-ylamino)pyrimidin-ium] hexa-molybdate",

abstract = "The title compound, (C8H8N5)2[Mo6O19], was prepared by reaction of Mo(CO)6 and dipyrimidylamine in refluxing toluene. The hexa-nuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intra-molecular N - H⋯N hydrogen bond and the cations are linked through self-complementary pairs of N - H⋯N hydrogen bonds into dimers across centres of inversion. The cations and anions are inter-linked through C - H⋯O contacts.",

author = "Yeh, \{Chun Wei\} and Lin, \{Chia Her\} and Chen, \{Jhy Der\}",

year = "2008",

doi = "10.1107/S1600536807062897",

language = "English",

volume = "64",

pages = "m41",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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T1 - Bis[2-(pyrimidin-2-ylamino)pyrimidin-ium] hexa-molybdate

AU - Yeh, Chun Wei

AU - Lin, Chia Her

AU - Chen, Jhy Der

PY - 2008

Y1 - 2008

N2 - The title compound, (C8H8N5)2[Mo6O19], was prepared by reaction of Mo(CO)6 and dipyrimidylamine in refluxing toluene. The hexa-nuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intra-molecular N - H⋯N hydrogen bond and the cations are linked through self-complementary pairs of N - H⋯N hydrogen bonds into dimers across centres of inversion. The cations and anions are inter-linked through C - H⋯O contacts.

AB - The title compound, (C8H8N5)2[Mo6O19], was prepared by reaction of Mo(CO)6 and dipyrimidylamine in refluxing toluene. The hexa-nuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intra-molecular N - H⋯N hydrogen bond and the cations are linked through self-complementary pairs of N - H⋯N hydrogen bonds into dimers across centres of inversion. The cations and anions are inter-linked through C - H⋯O contacts.

UR - https://www.scopus.com/pages/publications/37849012694

UR - https://www.scopus.com/pages/publications/37849012694#tab=citedBy

U2 - 10.1107/S1600536807062897

DO - 10.1107/S1600536807062897

M3 - Article

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SN - 1600-5368

VL - 64

SP - m41

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 1

ER -

Bis[2-(pyrimidin-2-ylamino)pyrimidin-ium] hexa-molybdate

Abstract

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