Bis[-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl- aluminium(III)]

Chen Yu Li; Chia Her Lin; Bao Tsan Ko

doi:10.1107/S1600536809018492

Bis[-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl- aluminium(III)]

Chen Yu Li, Chia Her Lin, Bao Tsan Ko^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The title complex, [A_l2(CH₃)₄(C ₁₃H₁₀N₃O)₂], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.

Original language	English
Pages (from-to)	m670
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	6
DOIs	https://doi.org/10.1107/S1600536809018492
Publication status	Published - 2009
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Bis[-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl- aluminium(III)]",

abstract = "The title complex, [Al2(CH3)4(C 13H10N3O)2], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.",

author = "Li, {Chen Yu} and Lin, {Chia Her} and Ko, {Bao Tsan}",

year = "2009",

doi = "10.1107/S1600536809018492",

language = "English",

volume = "65",

pages = "m670",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "6",

}

TY - JOUR

T1 - Bis[-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl- aluminium(III)]

AU - Li, Chen Yu

AU - Lin, Chia Her

AU - Ko, Bao Tsan

PY - 2009

Y1 - 2009

N2 - The title complex, [Al2(CH3)4(C 13H10N3O)2], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.

AB - The title complex, [Al2(CH3)4(C 13H10N3O)2], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 6

ER -

Bis[-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl- aluminium(III)]

Abstract

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