Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide

Chi Huan Li; Hui Ju Chuang; Chen Yu Li; Bao Tsan Ko; Chia Her Lin

doi:10.1039/c4py00528g

Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide

Chi Huan Li, Hui Ju Chuang, Chen Yu Li, Bao Tsan Ko^*, Chia Her Lin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

New bimetallic nickel, cobalt and zinc complexes bearing a bis(benzotriazole iminophenolate) ligand and ancillary acetate groups were developed for CO₂/epoxide copolymerization. Ni and Co complexes are active catalysts for the copolymerization of cyclohexene oxide (CHO) and CO ₂ without co-catalysts. Particularly, well-defined di-Ni 1 was found to effectively copolymerize CHO with CO₂, giving copolymers with a high molecular weight and a high carbonate linkage content. This is the first example of a dinuclear nickel acetate complex that is efficient for CO ₂/CHO copolymerization as well as for the formation of highly alternative poly(cyclohexene carbonate) in a controllable manner. This journal is

Original language	English
Pages (from-to)	4875-4878
Number of pages	4
Journal	Polymer Chemistry
Volume	5
Issue number	17
DOIs	https://doi.org/10.1039/c4py00528g
Publication status	Published - 2014 Sept 7
Externally published	Yes

ASJC Scopus subject areas

Bioengineering
Biochemistry
Polymers and Plastics
Organic Chemistry

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abstract = "New bimetallic nickel, cobalt and zinc complexes bearing a bis(benzotriazole iminophenolate) ligand and ancillary acetate groups were developed for CO2/epoxide copolymerization. Ni and Co complexes are active catalysts for the copolymerization of cyclohexene oxide (CHO) and CO 2 without co-catalysts. Particularly, well-defined di-Ni 1 was found to effectively copolymerize CHO with CO2, giving copolymers with a high molecular weight and a high carbonate linkage content. This is the first example of a dinuclear nickel acetate complex that is efficient for CO 2/CHO copolymerization as well as for the formation of highly alternative poly(cyclohexene carbonate) in a controllable manner. This journal is",

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T1 - Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide

AU - Li, Chi Huan

AU - Chuang, Hui Ju

AU - Li, Chen Yu

AU - Ko, Bao Tsan

AU - Lin, Chia Her

PY - 2014/9/7

Y1 - 2014/9/7

N2 - New bimetallic nickel, cobalt and zinc complexes bearing a bis(benzotriazole iminophenolate) ligand and ancillary acetate groups were developed for CO2/epoxide copolymerization. Ni and Co complexes are active catalysts for the copolymerization of cyclohexene oxide (CHO) and CO 2 without co-catalysts. Particularly, well-defined di-Ni 1 was found to effectively copolymerize CHO with CO2, giving copolymers with a high molecular weight and a high carbonate linkage content. This is the first example of a dinuclear nickel acetate complex that is efficient for CO 2/CHO copolymerization as well as for the formation of highly alternative poly(cyclohexene carbonate) in a controllable manner. This journal is

AB - New bimetallic nickel, cobalt and zinc complexes bearing a bis(benzotriazole iminophenolate) ligand and ancillary acetate groups were developed for CO2/epoxide copolymerization. Ni and Co complexes are active catalysts for the copolymerization of cyclohexene oxide (CHO) and CO 2 without co-catalysts. Particularly, well-defined di-Ni 1 was found to effectively copolymerize CHO with CO2, giving copolymers with a high molecular weight and a high carbonate linkage content. This is the first example of a dinuclear nickel acetate complex that is efficient for CO 2/CHO copolymerization as well as for the formation of highly alternative poly(cyclohexene carbonate) in a controllable manner. This journal is

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Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide

Abstract

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