Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature

Chun Wei Kuo; Min Tsang Hsieh; Shijay Gao; Yi Ming Shao; Ching Fa Yao; Kak Shan Shia

doi:10.3390/molecules171113662

Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature

Chun Wei Kuo
, Min Tsang Hsieh
, Shijay Gao
, Yi Ming Shao
, Ching Fa Yao
, Kak Shan Shia^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Upon treatment with phenyl dichlorophosphate (PhOP=OCl ₂) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.

Original language	English
Pages (from-to)	13662-13672
Number of pages	11
Journal	Molecules
Volume	17
Issue number	11
DOIs	https://doi.org/10.3390/molecules171113662
Publication status	Published - 2012 Nov

Keywords

Ambient temperature
Beckmann rearrangement
Ketoximes
Phenyl dichlorophosphate

ASJC Scopus subject areas

Analytical Chemistry
Chemistry (miscellaneous)
Molecular Medicine
Pharmaceutical Science
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry

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10.3390/molecules171113662

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title = "Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature",

abstract = "Upon treatment with phenyl dichlorophosphate (PhOP=OCl 2) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.",

keywords = "Ambient temperature, Beckmann rearrangement, Ketoximes, Phenyl dichlorophosphate",

author = "Kuo, \{Chun Wei\} and Hsieh, \{Min Tsang\} and Shijay Gao and Shao, \{Yi Ming\} and Yao, \{Ching Fa\} and Shia, \{Kak Shan\}",

year = "2012",

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T1 - Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature

AU - Kuo, Chun Wei

AU - Hsieh, Min Tsang

AU - Gao, Shijay

AU - Shao, Yi Ming

AU - Yao, Ching Fa

AU - Shia, Kak Shan

PY - 2012/11

Y1 - 2012/11

N2 - Upon treatment with phenyl dichlorophosphate (PhOP=OCl 2) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.

AB - Upon treatment with phenyl dichlorophosphate (PhOP=OCl 2) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.

KW - Ambient temperature

KW - Beckmann rearrangement

KW - Ketoximes

KW - Phenyl dichlorophosphate

UR - https://www.scopus.com/pages/publications/84870170640

UR - https://www.scopus.com/pages/publications/84870170640#tab=citedBy

U2 - 10.3390/molecules171113662

DO - 10.3390/molecules171113662

M3 - Article

C2 - 23169264

AN - SCOPUS:84870170640

SN - 1420-3049

VL - 17

SP - 13662

EP - 13672

JO - Molecules

JF - Molecules

IS - 11

ER -

Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature

Abstract

Keywords

ASJC Scopus subject areas

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