Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature

Chun Wei Kuo, Min Tsang Hsieh, Shijay Gao, Yi Ming Shao, Ching Fa Yao, Kak Shan Shia

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Upon treatment with phenyl dichlorophosphate (PhOP=OCl 2 ) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.

Original languageEnglish
Pages (from-to)13662-13672
Number of pages11
JournalMolecules
Volume17
Issue number11
DOIs
Publication statusPublished - 2012 Nov 1

Keywords

  • Ambient temperature
  • Beckmann rearrangement
  • Ketoximes
  • Phenyl dichlorophosphate

ASJC Scopus subject areas

  • Analytical Chemistry
  • Chemistry (miscellaneous)
  • Molecular Medicine
  • Pharmaceutical Science
  • Drug Discovery
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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