Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature

Chun Wei Kuo, Min Tsang Hsieh, Shijay Gao, Yi Ming Shao, Ching-Fa Yao, Kak Shan Shia

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Upon treatment with phenyl dichlorophosphate (PhOP=OCl 2 ) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.

Original languageEnglish
Pages (from-to)13662-13672
Number of pages11
JournalMolecules
Volume17
Issue number11
DOIs
Publication statusPublished - 2012 Nov 1

Fingerprint

Oximes
Amides
amides
ambient temperature
acetonitrile
Temperature
phenyl dichlorophosphate

Keywords

  • Ambient temperature
  • Beckmann rearrangement
  • Ketoximes
  • Phenyl dichlorophosphate

ASJC Scopus subject areas

  • Analytical Chemistry
  • Chemistry (miscellaneous)
  • Molecular Medicine
  • Pharmaceutical Science
  • Drug Discovery
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature. / Kuo, Chun Wei; Hsieh, Min Tsang; Gao, Shijay; Shao, Yi Ming; Yao, Ching-Fa; Shia, Kak Shan.

In: Molecules, Vol. 17, No. 11, 01.11.2012, p. 13662-13672.

Research output: Contribution to journalArticle

Kuo, Chun Wei ; Hsieh, Min Tsang ; Gao, Shijay ; Shao, Yi Ming ; Yao, Ching-Fa ; Shia, Kak Shan. / Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature. In: Molecules. 2012 ; Vol. 17, No. 11. pp. 13662-13672.
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