Azido(benzonitrile-κN)[hydridotris(pyrazol-1-yl-κN 2)borato](triphenyl-phosphine-κP)ruthenium(II)

Chiung Cheng Huang; Han Gung Chen; Yih Hsing Lo; Wen Rong Lai; Chia Her Lin

doi:10.1107/S1600536810021513

Azido(benzonitrile-κN)[hydridotris(pyrazol-1-yl-κN ²)borato](triphenyl-phosphine-κP)ruthenium(II)

Chiung Cheng Huang
, Han Gung Chen
, Yih Hsing Lo
, Wen Rong Lai
, Chia Her Lin

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Facile ligand substitution is observed when the ruthenium-azide complex, [RuN₃(Tp)(PPh₃)₂] [Tp,HB(pz)₃, pz = pyrazolyl, PPh₃ = triphenyl-phosphine] is treated with benzo-nitrile, yielding the title compound, [Ru(C₉H₁₀BN ₆)(N₃)(C₇H₅N)(C₁₈H ₁₅P)]. The asymmetric unit contains two crystallographically independent molecules. In each one, the Ru^II atom is six-coordinated in a distorted octa-hedral geometry by five N atoms from an htpb ligand, an azide ligand and a benzonitrile ligand and one P atom from a triphenyl-phosphine (tpp) ligand. The azide group is almost linear and is coordinated to Ru with an average Ru-N-N angle of 124.9 (3)°.

Original language	English
Pages (from-to)	m864
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	7
DOIs	https://doi.org/10.1107/S1600536810021513
Publication status	Published - 2010
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536810021513

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title = "Azido(benzonitrile-κN)[hydridotris(pyrazol-1-yl-κN 2)borato](triphenyl-phosphine-κP)ruthenium(II)",

abstract = "Facile ligand substitution is observed when the ruthenium-azide complex, [RuN3(Tp)(PPh3)2] [Tp,HB(pz)3, pz = pyrazolyl, PPh3 = triphenyl-phosphine] is treated with benzo-nitrile, yielding the title compound, [Ru(C9H10BN 6)(N3)(C7H5N)(C18H 15P)]. The asymmetric unit contains two crystallographically independent molecules. In each one, the RuII atom is six-coordinated in a distorted octa-hedral geometry by five N atoms from an htpb ligand, an azide ligand and a benzonitrile ligand and one P atom from a triphenyl-phosphine (tpp) ligand. The azide group is almost linear and is coordinated to Ru with an average Ru-N-N angle of 124.9 (3)°.",

author = "Huang, \{Chiung Cheng\} and Chen, \{Han Gung\} and Lo, \{Yih Hsing\} and Lai, \{Wen Rong\} and Lin, \{Chia Her\}",

year = "2010",

doi = "10.1107/S1600536810021513",

language = "English",

volume = "66",

pages = "m864",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

}

TY - JOUR

T1 - Azido(benzonitrile-κN)[hydridotris(pyrazol-1-yl-κN 2)borato](triphenyl-phosphine-κP)ruthenium(II)

AU - Huang, Chiung Cheng

AU - Chen, Han Gung

AU - Lo, Yih Hsing

AU - Lai, Wen Rong

AU - Lin, Chia Her

PY - 2010

Y1 - 2010

N2 - Facile ligand substitution is observed when the ruthenium-azide complex, [RuN3(Tp)(PPh3)2] [Tp,HB(pz)3, pz = pyrazolyl, PPh3 = triphenyl-phosphine] is treated with benzo-nitrile, yielding the title compound, [Ru(C9H10BN 6)(N3)(C7H5N)(C18H 15P)]. The asymmetric unit contains two crystallographically independent molecules. In each one, the RuII atom is six-coordinated in a distorted octa-hedral geometry by five N atoms from an htpb ligand, an azide ligand and a benzonitrile ligand and one P atom from a triphenyl-phosphine (tpp) ligand. The azide group is almost linear and is coordinated to Ru with an average Ru-N-N angle of 124.9 (3)°.

AB - Facile ligand substitution is observed when the ruthenium-azide complex, [RuN3(Tp)(PPh3)2] [Tp,HB(pz)3, pz = pyrazolyl, PPh3 = triphenyl-phosphine] is treated with benzo-nitrile, yielding the title compound, [Ru(C9H10BN 6)(N3)(C7H5N)(C18H 15P)]. The asymmetric unit contains two crystallographically independent molecules. In each one, the RuII atom is six-coordinated in a distorted octa-hedral geometry by five N atoms from an htpb ligand, an azide ligand and a benzonitrile ligand and one P atom from a triphenyl-phosphine (tpp) ligand. The azide group is almost linear and is coordinated to Ru with an average Ru-N-N angle of 124.9 (3)°.

UR - https://www.scopus.com/pages/publications/77954407964

UR - https://www.scopus.com/pages/publications/77954407964#tab=citedBy

U2 - 10.1107/S1600536810021513

DO - 10.1107/S1600536810021513

M3 - Article

AN - SCOPUS:77954407964

SN - 1600-5368

VL - 66

SP - m864

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

Azido(benzonitrile-κN)[hydridotris(pyrazol-1-yl-κN ²)borato](triphenyl-phosphine-κP)ruthenium(II)

Abstract

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