Azido-(1,1-diphenyl-methanimine-N)[hydridotris(pyrazolyl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II) diethyl ether solvate

Chia Her Lin; Ting Shen Kuo; Hung Chun Tong; Chih Yung Chen Hsu; Yih Hsing Lo

doi:10.1107/S1600536808036039

Azido-(1,1-diphenyl-methanimine-N)[hydridotris(pyrazolyl-N κ²)borato](triphenyl-phosphine-P)ruthenium(II) diethyl ether solvate

Chia Her Lin, Ting Shen Kuo, Hung Chun Tong, Chih Yung Chen Hsu, Yih Hsing Lo^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The reaction of [RuCl(C9H10BN6)(C18H15P)2] with benzo-phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C9H10BN6)(N3)(HN=CPh2)(C18H15P)]·C4H10O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenyl-phosphine ligand, one N atom of the azide anion and one N atom of the benzophenone-imine ligand in a slightly distorted octa-hedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru - N - N angle of 125.9 (3)°. There is a small difference between the N - N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom.

Original language	English
Pages (from-to)	m1511-m1512
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	12
DOIs	https://doi.org/10.1107/S1600536808036039
Publication status	Published - 2008
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536808036039

Cite this

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title = "Azido-(1,1-diphenyl-methanimine-N)[hydridotris(pyrazolyl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II) diethyl ether solvate",

abstract = "The reaction of [RuCl(C9H10BN6)(C18H15P)2] with benzo-phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C9H10BN6)(N3)(HN=CPh2)(C18H15P)]·C4H10O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenyl-phosphine ligand, one N atom of the azide anion and one N atom of the benzophenone-imine ligand in a slightly distorted octa-hedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru - N - N angle of 125.9 (3)°. There is a small difference between the N - N distances [1.200 (5) and 1.164 (5) {\AA}], the longer bond being adjacent to the Ru atom.",

author = "Lin, {Chia Her} and Kuo, {Ting Shen} and Tong, {Hung Chun} and {Chen Hsu}, {Chih Yung} and Lo, {Yih Hsing}",

year = "2008",

doi = "10.1107/S1600536808036039",

language = "English",

volume = "64",

pages = "m1511--m1512",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

}

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T1 - Azido-(1,1-diphenyl-methanimine-N)[hydridotris(pyrazolyl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II) diethyl ether solvate

AU - Lin, Chia Her

AU - Kuo, Ting Shen

AU - Tong, Hung Chun

AU - Chen Hsu, Chih Yung

AU - Lo, Yih Hsing

PY - 2008

Y1 - 2008

N2 - The reaction of [RuCl(C9H10BN6)(C18H15P)2] with benzo-phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C9H10BN6)(N3)(HN=CPh2)(C18H15P)]·C4H10O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenyl-phosphine ligand, one N atom of the azide anion and one N atom of the benzophenone-imine ligand in a slightly distorted octa-hedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru - N - N angle of 125.9 (3)°. There is a small difference between the N - N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom.

AB - The reaction of [RuCl(C9H10BN6)(C18H15P)2] with benzo-phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C9H10BN6)(N3)(HN=CPh2)(C18H15P)]·C4H10O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenyl-phosphine ligand, one N atom of the azide anion and one N atom of the benzophenone-imine ligand in a slightly distorted octa-hedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru - N - N angle of 125.9 (3)°. There is a small difference between the N - N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom.

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ER -

Azido-(1,1-diphenyl-methanimine-N)[hydridotris(pyrazolyl-N κ²)borato](triphenyl-phosphine-P)ruthenium(II) diethyl ether solvate

Abstract

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CCDC 712279: Experimental Crystal Structure Determination

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Azido-(1,1-diphenyl-methanimine-N)[hydridotris(pyrazolyl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II) diethyl ether solvate

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 712279: Experimental Crystal Structure Determination

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Azido-(1,1-diphenyl-methanimine-N)[hydridotris(pyrazolyl-N κ²)borato](triphenyl-phosphine-P)ruthenium(II) diethyl ether solvate