Azido-(1,1-diphenyl-methanimine-N)[hydridotris(pyrazolyl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II) diethyl ether solvate

Chia Her Lin, Ting Shen Kuo, Hung Chun Tong, Chih Yung Chen Hsu, Yih Hsing Lo*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

The reaction of [RuCl(C9H10BN6)(C18H15P)2] with benzo-phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C9H10BN6)(N3)(HN=CPh2)(C18H15P)]·C4H10O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenyl-phosphine ligand, one N atom of the azide anion and one N atom of the benzophenone-imine ligand in a slightly distorted octa-hedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru - N - N angle of 125.9 (3)°. There is a small difference between the N - N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom.

Original languageEnglish
Pages (from-to)m1511-m1512
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number12
DOIs
Publication statusPublished - 2008
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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