Asymmetric epoxidation of allylic alcohols catalyzed by new chiral vanadium(V) complexes

Hsyueh Liang Wu; Biing Jiun Uang

doi:10.1016/S0957-4166(02)00741-3

Asymmetric epoxidation of allylic alcohols catalyzed by new chiral vanadium(V) complexes

Hsyueh Liang Wu, Biing Jiun Uang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

Vanadium catalysts bearing (+)-ketopinic acid-based chiral hydroxamic acids as constituent ligands are investigated in the asymmetric epoxidation of allylic alcohols. Chiral ligands lacking an N-substituent and those having a bulkier aryl group in the bornane skeleton provided better selectivity.

Original language	English
Pages (from-to)	2625-2628
Number of pages	4
Journal	Tetrahedron Asymmetry
Volume	13
Issue number	24
DOIs	https://doi.org/10.1016/S0957-4166(02)00741-3
Publication status	Published - 2002 Dec 9
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1016/S0957-4166(02)00741-3

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title = "Asymmetric epoxidation of allylic alcohols catalyzed by new chiral vanadium(V) complexes",

abstract = "Vanadium catalysts bearing (+)-ketopinic acid-based chiral hydroxamic acids as constituent ligands are investigated in the asymmetric epoxidation of allylic alcohols. Chiral ligands lacking an N-substituent and those having a bulkier aryl group in the bornane skeleton provided better selectivity.",

author = "Wu, {Hsyueh Liang} and Uang, {Biing Jiun}",

note = "Funding Information: We thank the National Science Council, Republic of China for the financial support.",

year = "2002",

month = dec,

day = "9",

doi = "10.1016/S0957-4166(02)00741-3",

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T1 - Asymmetric epoxidation of allylic alcohols catalyzed by new chiral vanadium(V) complexes

AU - Wu, Hsyueh Liang

AU - Uang, Biing Jiun

N1 - Funding Information: We thank the National Science Council, Republic of China for the financial support.

PY - 2002/12/9

Y1 - 2002/12/9

N2 - Vanadium catalysts bearing (+)-ketopinic acid-based chiral hydroxamic acids as constituent ligands are investigated in the asymmetric epoxidation of allylic alcohols. Chiral ligands lacking an N-substituent and those having a bulkier aryl group in the bornane skeleton provided better selectivity.

AB - Vanadium catalysts bearing (+)-ketopinic acid-based chiral hydroxamic acids as constituent ligands are investigated in the asymmetric epoxidation of allylic alcohols. Chiral ligands lacking an N-substituent and those having a bulkier aryl group in the bornane skeleton provided better selectivity.

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U2 - 10.1016/S0957-4166(02)00741-3

DO - 10.1016/S0957-4166(02)00741-3

M3 - Article

AN - SCOPUS:0037049386

SN - 0957-4166

VL - 13

SP - 2625

EP - 2628

JO - Tetrahedron Asymmetry

JF - Tetrahedron Asymmetry

IS - 24

ER -

Asymmetric epoxidation of allylic alcohols catalyzed by new chiral vanadium(V) complexes

Abstract

ASJC Scopus subject areas

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