Asymmetric epoxidation of allylic alcohols catalyzed by new chiral vanadium(V) complexes

Hsyueh-Liang Wu, Biing Jiun Uang

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Vanadium catalysts bearing (+)-ketopinic acid-based chiral hydroxamic acids as constituent ligands are investigated in the asymmetric epoxidation of allylic alcohols. Chiral ligands lacking an N-substituent and those having a bulkier aryl group in the bornane skeleton provided better selectivity.

Original languageEnglish
Pages (from-to)2625-2628
Number of pages4
JournalTetrahedron Asymmetry
Volume13
Issue number24
DOIs
Publication statusPublished - 2002 Dec 9

Fingerprint

Vanadium
epoxidation
Epoxidation
vanadium
alcohols
Alcohols
Bearings (structural)
Ligands
Hydroxamic Acids
ligands
acids
Acids
musculoskeletal system
selectivity
catalysts
Catalysts
allyl alcohol
oligomycin sensitivity-conferring protein
camphane
ketopinic acid

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Asymmetric epoxidation of allylic alcohols catalyzed by new chiral vanadium(V) complexes. / Wu, Hsyueh-Liang; Uang, Biing Jiun.

In: Tetrahedron Asymmetry, Vol. 13, No. 24, 09.12.2002, p. 2625-2628.

Research output: Contribution to journalArticle

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