Assembly of a water-insoluble strontium metal-organic framework with luminescent properties

Sheng Han Lo; Hsin Kuan Liu; Jun Xiang Zhan; Wei Cheng Lin; Ching Che Kao; Chia Her Lin; Vítězslav Zima

doi:10.1016/j.inoche.2011.06.017

Assembly of a water-insoluble strontium metal-organic framework with luminescent properties

Sheng Han Lo, Hsin Kuan Liu, Jun Xiang Zhan, Wei Cheng Lin, Ching Che Kao, Chia Her Lin^*, Vítězslav Zima

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

A new strontium metal-organic framework, [Sr₂(BTEC)(H ₂O)₄]2H₂O (1) (H₄BTEC = benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437 nm after dehydration.

Original language	English
Pages (from-to)	1602-1605
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	10
DOIs	https://doi.org/10.1016/j.inoche.2011.06.017
Publication status	Published - 2011 Oct
Externally published	Yes

Keywords

Luminescent
Metal-organic framework
Strontium complex
Water-insoluble

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2011.06.017

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@article{12478d6b39f74fb6a83ba4fbb0152410,

title = "Assembly of a water-insoluble strontium metal-organic framework with luminescent properties",

abstract = "A new strontium metal-organic framework, [Sr2(BTEC)(H 2O)4]2H2O (1) (H4BTEC = benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437 nm after dehydration.",

keywords = "Luminescent, Metal-organic framework, Strontium complex, Water-insoluble",

author = "Lo, {Sheng Han} and Liu, {Hsin Kuan} and Zhan, {Jun Xiang} and Lin, {Wei Cheng} and Kao, {Ching Che} and Lin, {Chia Her} and V{\'i}t{\v e}zslav Zima",

note = "Funding Information: We gratefully acknowledge financial support from the National Science Council, Taiwan ( NSC99-2113-M-033-005-MY2 ). V. Z. thanks to the Czech Science Foundation (Project no. 203/08/0208 ) for the financial support. ",

year = "2011",

month = oct,

doi = "10.1016/j.inoche.2011.06.017",

language = "English",

volume = "14",

pages = "1602--1605",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier BV",

number = "10",

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TY - JOUR

T1 - Assembly of a water-insoluble strontium metal-organic framework with luminescent properties

AU - Lo, Sheng Han

AU - Liu, Hsin Kuan

AU - Zhan, Jun Xiang

AU - Lin, Wei Cheng

AU - Kao, Ching Che

AU - Lin, Chia Her

AU - Zima, Vítězslav

N1 - Funding Information: We gratefully acknowledge financial support from the National Science Council, Taiwan ( NSC99-2113-M-033-005-MY2 ). V. Z. thanks to the Czech Science Foundation (Project no. 203/08/0208 ) for the financial support.

PY - 2011/10

Y1 - 2011/10

N2 - A new strontium metal-organic framework, [Sr2(BTEC)(H 2O)4]2H2O (1) (H4BTEC = benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437 nm after dehydration.

AB - A new strontium metal-organic framework, [Sr2(BTEC)(H 2O)4]2H2O (1) (H4BTEC = benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437 nm after dehydration.

KW - Luminescent

KW - Metal-organic framework

KW - Strontium complex

KW - Water-insoluble

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U2 - 10.1016/j.inoche.2011.06.017

DO - 10.1016/j.inoche.2011.06.017

M3 - Article

AN - SCOPUS:80052774793

SN - 1387-7003

VL - 14

SP - 1602

EP - 1605

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -

Assembly of a water-insoluble strontium metal-organic framework with luminescent properties

Abstract

Keywords

ASJC Scopus subject areas

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