An unprecedented hydride abstraction from tricarbonyl[ethyl exo-3-[1-4- η-1,3-cyclohexadien-5-yl]propionate]iron complex

Ming Chang P. Yeh; Bi Ai Sheu; Ming Yuan Wang

doi:10.1016/S0040-4039(98)01229-5

An unprecedented hydride abstraction from tricarbonyl[ethyl exo-3-[1-4- η-1,3-cyclohexadien-5-yl]propionate]iron complex

Ming Chang P. Yeh^*, Bi Ai Sheu, Ming Yuan Wang

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The addition of triphenylcarbenium hexafluorophosphate to the title complex gives tricarbonyl(η⁵-cyclohexadienylium)iron hexafluorophosphate with a side chain at the C-1 position of the ring. Intramolecular cyclization of the cation using sodium- or calcium- hydride generates a heterospiro[4,5]decane derivative.

Original language	English
Pages (from-to)	5987-5990
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	33
DOIs	https://doi.org/10.1016/S0040-4039(98)01229-5
Publication status	Published - 1998 Aug 13

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(98)01229-5

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abstract = "The addition of triphenylcarbenium hexafluorophosphate to the title complex gives tricarbonyl(η5-cyclohexadienylium)iron hexafluorophosphate with a side chain at the C-1 position of the ring. Intramolecular cyclization of the cation using sodium- or calcium- hydride generates a heterospiro[4,5]decane derivative.",

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AU - Sheu, Bi Ai

AU - Wang, Ming Yuan

PY - 1998/8/13

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N2 - The addition of triphenylcarbenium hexafluorophosphate to the title complex gives tricarbonyl(η5-cyclohexadienylium)iron hexafluorophosphate with a side chain at the C-1 position of the ring. Intramolecular cyclization of the cation using sodium- or calcium- hydride generates a heterospiro[4,5]decane derivative.

AB - The addition of triphenylcarbenium hexafluorophosphate to the title complex gives tricarbonyl(η5-cyclohexadienylium)iron hexafluorophosphate with a side chain at the C-1 position of the ring. Intramolecular cyclization of the cation using sodium- or calcium- hydride generates a heterospiro[4,5]decane derivative.

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ER -

An unprecedented hydride abstraction from tricarbonyl[ethyl exo-3-[1-4- η-1,3-cyclohexadien-5-yl]propionate]iron complex

Abstract

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