An unprecedented hydride abstraction from tricarbonyl[ethyl exo-3-[1-4- η-1,3-cyclohexadien-5-yl]propionate]iron complex

Ming-Chang P. Yeh, Bi Ai Sheu, Ming Yuan Wang

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The addition of triphenylcarbenium hexafluorophosphate to the title complex gives tricarbonyl(η5-cyclohexadienylium)iron hexafluorophosphate with a side chain at the C-1 position of the ring. Intramolecular cyclization of the cation using sodium- or calcium- hydride generates a heterospiro[4,5]decane derivative.

Original languageEnglish
Pages (from-to)5987-5990
Number of pages4
JournalTetrahedron Letters
Volume39
Issue number33
DOIs
Publication statusPublished - 1998 Aug 13

Fingerprint

Cyclization
Propionates
Hydrides
Cations
Iron
Sodium
Calcium
Derivatives
decane

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

An unprecedented hydride abstraction from tricarbonyl[ethyl exo-3-[1-4- η-1,3-cyclohexadien-5-yl]propionate]iron complex. / Yeh, Ming-Chang P.; Sheu, Bi Ai; Wang, Ming Yuan.

In: Tetrahedron Letters, Vol. 39, No. 33, 13.08.1998, p. 5987-5990.

Research output: Contribution to journalArticle

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