Amphoteric water-soluble copolymer for barium titanate slurries. I. Synthesis and dispersing ability

Lung Pin Chen; Kung Chung Hsu

doi:10.1002/app.21584

Amphoteric water-soluble copolymer for barium titanate slurries. I. Synthesis and dispersing ability

Lung Pin Chen, Kung Chung Hsu^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

An amphoteric water-soluble copolymer, polyacrylamide/[α-N,N- dimethyl-N-(3-(β-carboxylate)acrylamino)propyl] ammonium ethanate (PAM/DAE) was synthesized and used as a dispersion agent for BaTiO₃ particles. PAM/DAE was prepared from acrylamide and [α-N,N-dimethyl-N-(3-(β- carboxylate)acrylamino)propyl] ammonium ethanate in a basic condition through a free-radical polymerization. The structure of this copolymer was verified by IR and ¹H-NMR spectra. The dispersing effects of PAM/DAE were examined by measuring the viscosity and sedimentation of BaTiO₃ suspensions, and by analyzing the particle size. The results indicate that this copolymer could uniformly disperse the particles, and the resulting suspensions were less viscous, more stabilized, and contained powder with smaller particle size. The dispersing/stabilizing ability of PAM/DAE is close to, or slightly better than, that of a commercial dispersant, ammonium salt of poly(methacrylic acid).

Original language	English
Pages (from-to)	1443-1450
Number of pages	8
Journal	Journal of Applied Polymer Science
Volume	96
Issue number	4
DOIs	https://doi.org/10.1002/app.21584
Publication status	Published - 2005 May 15

Keywords

Barium titanate
Dispersions
Polyelectrolytes
Structure
Synthesis

ASJC Scopus subject areas

Chemistry(all)
Surfaces, Coatings and Films
Polymers and Plastics
Materials Chemistry

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title = "Amphoteric water-soluble copolymer for barium titanate slurries. I. Synthesis and dispersing ability",

abstract = "An amphoteric water-soluble copolymer, polyacrylamide/[α-N,N- dimethyl-N-(3-(β-carboxylate)acrylamino)propyl] ammonium ethanate (PAM/DAE) was synthesized and used as a dispersion agent for BaTiO3 particles. PAM/DAE was prepared from acrylamide and [α-N,N-dimethyl-N-(3-(β- carboxylate)acrylamino)propyl] ammonium ethanate in a basic condition through a free-radical polymerization. The structure of this copolymer was verified by IR and 1H-NMR spectra. The dispersing effects of PAM/DAE were examined by measuring the viscosity and sedimentation of BaTiO3 suspensions, and by analyzing the particle size. The results indicate that this copolymer could uniformly disperse the particles, and the resulting suspensions were less viscous, more stabilized, and contained powder with smaller particle size. The dispersing/stabilizing ability of PAM/DAE is close to, or slightly better than, that of a commercial dispersant, ammonium salt of poly(methacrylic acid).",

keywords = "Barium titanate, Dispersions, Polyelectrolytes, Structure, Synthesis",

author = "Chen, {Lung Pin} and Hsu, {Kung Chung}",

year = "2005",

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doi = "10.1002/app.21584",

language = "English",

volume = "96",

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AU - Chen, Lung Pin

AU - Hsu, Kung Chung

PY - 2005/5/15

Y1 - 2005/5/15

N2 - An amphoteric water-soluble copolymer, polyacrylamide/[α-N,N- dimethyl-N-(3-(β-carboxylate)acrylamino)propyl] ammonium ethanate (PAM/DAE) was synthesized and used as a dispersion agent for BaTiO3 particles. PAM/DAE was prepared from acrylamide and [α-N,N-dimethyl-N-(3-(β- carboxylate)acrylamino)propyl] ammonium ethanate in a basic condition through a free-radical polymerization. The structure of this copolymer was verified by IR and 1H-NMR spectra. The dispersing effects of PAM/DAE were examined by measuring the viscosity and sedimentation of BaTiO3 suspensions, and by analyzing the particle size. The results indicate that this copolymer could uniformly disperse the particles, and the resulting suspensions were less viscous, more stabilized, and contained powder with smaller particle size. The dispersing/stabilizing ability of PAM/DAE is close to, or slightly better than, that of a commercial dispersant, ammonium salt of poly(methacrylic acid).

AB - An amphoteric water-soluble copolymer, polyacrylamide/[α-N,N- dimethyl-N-(3-(β-carboxylate)acrylamino)propyl] ammonium ethanate (PAM/DAE) was synthesized and used as a dispersion agent for BaTiO3 particles. PAM/DAE was prepared from acrylamide and [α-N,N-dimethyl-N-(3-(β- carboxylate)acrylamino)propyl] ammonium ethanate in a basic condition through a free-radical polymerization. The structure of this copolymer was verified by IR and 1H-NMR spectra. The dispersing effects of PAM/DAE were examined by measuring the viscosity and sedimentation of BaTiO3 suspensions, and by analyzing the particle size. The results indicate that this copolymer could uniformly disperse the particles, and the resulting suspensions were less viscous, more stabilized, and contained powder with smaller particle size. The dispersing/stabilizing ability of PAM/DAE is close to, or slightly better than, that of a commercial dispersant, ammonium salt of poly(methacrylic acid).

KW - Barium titanate

KW - Dispersions

KW - Polyelectrolytes

KW - Structure

KW - Synthesis

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Amphoteric water-soluble copolymer for barium titanate slurries. I. Synthesis and dispersing ability

Abstract

Keywords

ASJC Scopus subject areas

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