Ambiphilicity of a mononuclear cobalt(iii) superoxo complex

Ting Yi Chen; Po Hsun Ho; Can Jerome Spyra; Franc Meyer; Eckhard Bill; Shengfa Ye; Way Zen Lee

doi:10.1039/d0cc05337f

Ambiphilicity of a mononuclear cobalt(iii) superoxo complex

Ting Yi Chen, Po Hsun Ho, Can Jerome Spyra, Franc Meyer^*, Eckhard Bill, Shengfa Ye^*, Way Zen Lee^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Addition of HOTf to a mixture of CoIII(BDPP)(O2) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp∗2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.

Original language	English
Pages (from-to)	14821-14824
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	94
DOIs	https://doi.org/10.1039/d0cc05337f
Publication status	Published - 2020 Dec 7

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d0cc05337f

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title = "Ambiphilicity of a mononuclear cobalt(iii) superoxo complex",

abstract = "Addition of HOTf to a mixture of CoIII(BDPP)(O2) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp∗2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.",

author = "Chen, {Ting Yi} and Ho, {Po Hsun} and Spyra, {Can Jerome} and Franc Meyer and Eckhard Bill and Shengfa Ye and Lee, {Way Zen}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

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doi = "10.1039/d0cc05337f",

language = "English",

volume = "56",

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T1 - Ambiphilicity of a mononuclear cobalt(iii) superoxo complex

AU - Chen, Ting Yi

AU - Ho, Po Hsun

AU - Spyra, Can Jerome

AU - Meyer, Franc

AU - Bill, Eckhard

AU - Ye, Shengfa

AU - Lee, Way Zen

PY - 2020/12/7

Y1 - 2020/12/7

N2 - Addition of HOTf to a mixture of CoIII(BDPP)(O2) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp∗2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.

AB - Addition of HOTf to a mixture of CoIII(BDPP)(O2) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp∗2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.

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DO - 10.1039/d0cc05337f

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C2 - 33151205

AN - SCOPUS:85096885057

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SP - 14821

EP - 14824

JO - Chemical Communications

JF - Chemical Communications

IS - 94

ER -

Ambiphilicity of a mononuclear cobalt(iii) superoxo complex

Abstract

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