Abstract
An organocuprate(III) complex, [Cu(TMSPS3)(CH2CN)]- (2), was identified along with a sequential derivative, [Cu(TMSPS3)(CN)]- (3), and an intermediate, [Cu(TMSPS3)(HN=PPh3)] (4), formed in a relative transformation. Apical ligands among these complexes all strongly associate with a robust trigonal copper(III) platform. The nature of the ligand binding was spectroscopically and computationally investigated through a series of copper(III) complexes. The bonding along the principal C3 axis is adaptable, and σ interaction dominates the axial ligand coordination, where the cyanomethyl group exhibits the strongest bonding. Complex 2 is a scarce example of a thermostable aliphatic organocuprate(III) compound, which sheds some light on the organocopper(III) chemistry widely involved in many copper-mediated catalyses.
| Original language | English |
|---|---|
| Pages (from-to) | 22-26 |
| Number of pages | 5 |
| Journal | Inorganic Chemistry |
| Volume | 58 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2019 Jan 7 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
Cite this
Ambient Stable Cyanomethylcopper(III) Complex : A Strong Cu-Csp3Bond Supported by a PS3-Tripodal Chelator. / Chang, Hao Ching; Chang, Ya Fan; Lin, Sheng Hsiang; Lin, Tsung Han; Lee, Way Zen.
In: Inorganic Chemistry, Vol. 58, No. 1, 07.01.2019, p. 22-26.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Ambient Stable Cyanomethylcopper(III) Complex
T2 - A Strong Cu-Csp3Bond Supported by a PS3-Tripodal Chelator
AU - Chang, Hao Ching
AU - Chang, Ya Fan
AU - Lin, Sheng Hsiang
AU - Lin, Tsung Han
AU - Lee, Way Zen
PY - 2019/1/7
Y1 - 2019/1/7
N2 - An organocuprate(III) complex, [Cu(TMSPS3)(CH2CN)]- (2), was identified along with a sequential derivative, [Cu(TMSPS3)(CN)]- (3), and an intermediate, [Cu(TMSPS3)(HN=PPh3)] (4), formed in a relative transformation. Apical ligands among these complexes all strongly associate with a robust trigonal copper(III) platform. The nature of the ligand binding was spectroscopically and computationally investigated through a series of copper(III) complexes. The bonding along the principal C3 axis is adaptable, and σ interaction dominates the axial ligand coordination, where the cyanomethyl group exhibits the strongest bonding. Complex 2 is a scarce example of a thermostable aliphatic organocuprate(III) compound, which sheds some light on the organocopper(III) chemistry widely involved in many copper-mediated catalyses.
AB - An organocuprate(III) complex, [Cu(TMSPS3)(CH2CN)]- (2), was identified along with a sequential derivative, [Cu(TMSPS3)(CN)]- (3), and an intermediate, [Cu(TMSPS3)(HN=PPh3)] (4), formed in a relative transformation. Apical ligands among these complexes all strongly associate with a robust trigonal copper(III) platform. The nature of the ligand binding was spectroscopically and computationally investigated through a series of copper(III) complexes. The bonding along the principal C3 axis is adaptable, and σ interaction dominates the axial ligand coordination, where the cyanomethyl group exhibits the strongest bonding. Complex 2 is a scarce example of a thermostable aliphatic organocuprate(III) compound, which sheds some light on the organocopper(III) chemistry widely involved in many copper-mediated catalyses.
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UR - http://www.scopus.com/inward/citedby.url?scp=85058643202&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.8b02511
DO - 10.1021/acs.inorgchem.8b02511
M3 - Article
VL - 58
SP - 22
EP - 26
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 1
ER -