Alkylation of the (η4-cyclohexa-1,3-diene) (η5-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl

Ming Chang P. Yeh; Chung Jy Tsou; Chong Nan Chuang; Hwei Chi Lin

doi:10.1039/C39920000890

Alkylation of the (η⁴-cyclohexa-1,3-diene) (η⁵-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl

Ming Chang P. Yeh^*, Chung Jy Tsou, Chong Nan Chuang, Hwei Chi Lin

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)₂(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

Original language	English
Pages (from-to)	890-891
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/C39920000890
Publication status	Published - 1992

ASJC Scopus subject areas

Molecular Medicine

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Alkylation of the (η⁴-cyclohexa-1,3-diene) (η⁵-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl. / Yeh, Ming Chang P.; Tsou, Chung Jy; Chuang, Chong Nan et al.
In: Journal of the Chemical Society, Chemical Communications, No. 12, 1992, p. 890-891.

Research output: Contribution to journal › Article › peer-review

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title = "Alkylation of the (η4-cyclohexa-1,3-diene) (η5-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl",

abstract = "The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)2(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.",

author = "Yeh, {Ming Chang P.} and Tsou, {Chung Jy} and Chuang, {Chong Nan} and Lin, {Hwei Chi}",

year = "1992",

doi = "10.1039/C39920000890",

language = "English",

pages = "890--891",

journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - Alkylation of the (η4-cyclohexa-1,3-diene) (η5-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl

AU - Yeh, Ming Chang P.

AU - Tsou, Chung Jy

AU - Chuang, Chong Nan

AU - Lin, Hwei Chi

PY - 1992

Y1 - 1992

N2 - The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)2(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

AB - The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)2(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

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U2 - 10.1039/C39920000890

DO - 10.1039/C39920000890

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SP - 890

EP - 891

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 12

ER -

Alkylation of the (η⁴-cyclohexa-1,3-diene) (η⁵-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl

Abstract

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