Alkylation of the (η4-cyclohexa-1,3-diene) (η5-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl

Ming Chang P. Yeh, Chung Jy Tsou, Chong Nan Chuang, Hwei Chi Lin

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)2(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

Original languageEnglish
Pages (from-to)890-891
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number12
DOIs
Publication statusPublished - 1992 Dec 1

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Molybdenum
Cyclization
Alkylation
Lactones
Carbon Monoxide
Cations
Zinc
Copper
Positive ions
Ligands
Derivatives
Acids
propionic acid

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

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title = "Alkylation of the (η4-cyclohexa-1,3-diene) (η5-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl",
abstract = "The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)2(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.",
author = "Yeh, {Ming Chang P.} and Tsou, {Chung Jy} and Chuang, {Chong Nan} and Lin, {Hwei Chi}",
year = "1992",
month = "12",
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doi = "10.1039/C39920000890",
language = "English",
pages = "890--891",
journal = "Chemical Communications",
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T1 - Alkylation of the (η4-cyclohexa-1,3-diene) (η5-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl

AU - Yeh, Ming Chang P.

AU - Tsou, Chung Jy

AU - Chuang, Chong Nan

AU - Lin, Hwei Chi

PY - 1992/12/1

Y1 - 1992/12/1

N2 - The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)2(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

AB - The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)2(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

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