Alkylation of the (η4-cyclohexa-1,3-diene) (η5-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl

Ming Chang P. Yeh, Chung Jy Tsou, Chong Nan Chuang, Hwei Chi Lin

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)2(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

Original languageEnglish
Pages (from-to)890-891
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number12
DOIs
Publication statusPublished - 1992 Dec 1

ASJC Scopus subject areas

  • Molecular Medicine

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