Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes

Ming Chang P. Yeh; Peng Yu Sheu; Jin Xuan Ho; Yi Lin Chiang; Dai Yu Chiu; U. Narasimha Rao

doi:10.1016/S0022-328X(03)00219-5

Addition reactions of lithiodimethylphenylsilane to (η⁴-1,3-diene)-Fe(CO)₃ and (η⁶-arene)Cr(CO)₃ complexes

Ming Chang P. Yeh^*, Peng Yu Sheu, Jin Xuan Ho, Yi Lin Chiang, Dai Yu Chiu, U. Narasimha Rao

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Treatments of (η⁴-cyclohexa-1,3-diene)Fe(CO)₃ complex with 1.2 equivalents of PhMe₂SiLi, followed by quenching the reactive intermediate with CF₃COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η⁴-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)₃ complex as the major product. Additions of the silyl anion to (η⁶-arene)Cr(CO)₃ and (η⁶-cyclohepta-1,3,5-triene)Cr(CO)₃ complexes produce dienylsilanes after acid quenching.

Original language	English
Pages (from-to)	13-20
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	675
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(03)00219-5
Publication status	Published - 2003 May 30

Keywords

Arene
Chromium
Cyclohexadiene
Iron
Silane

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(03)00219-5

Cite this

@article{3369373c9b6c484ab7f44bb0b1d07484,

title = "Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes",

abstract = "Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)3 complex as the major product. Additions of the silyl anion to (η6-arene)Cr(CO)3 and (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes produce dienylsilanes after acid quenching.",

keywords = "Arene, Chromium, Cyclohexadiene, Iron, Silane",

author = "Yeh, {Ming Chang P.} and Sheu, {Peng Yu} and Ho, {Jin Xuan} and Chiang, {Yi Lin} and Chiu, {Dai Yu} and {Narasimha Rao}, U.",

note = "Funding Information: This work was supported by grants from National Taiwan Normal University (ORD91-1) and the National Science Council (NSC 90-2113-M-003-008). ",

year = "2003",

month = may,

day = "30",

doi = "10.1016/S0022-328X(03)00219-5",

language = "English",

volume = "675",

pages = "13--20",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes

AU - Yeh, Ming Chang P.

AU - Sheu, Peng Yu

AU - Ho, Jin Xuan

AU - Chiang, Yi Lin

AU - Chiu, Dai Yu

AU - Narasimha Rao, U.

N1 - Funding Information: This work was supported by grants from National Taiwan Normal University (ORD91-1) and the National Science Council (NSC 90-2113-M-003-008).

PY - 2003/5/30

Y1 - 2003/5/30

N2 - Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)3 complex as the major product. Additions of the silyl anion to (η6-arene)Cr(CO)3 and (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes produce dienylsilanes after acid quenching.

AB - Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)3 complex as the major product. Additions of the silyl anion to (η6-arene)Cr(CO)3 and (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes produce dienylsilanes after acid quenching.

KW - Arene

KW - Chromium

KW - Cyclohexadiene

KW - Iron

KW - Silane

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U2 - 10.1016/S0022-328X(03)00219-5

DO - 10.1016/S0022-328X(03)00219-5

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SN - 0022-328X

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EP - 20

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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