Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes

Ming-Chang P. Yeh, Peng Yu Sheu, Jin Xuan Ho, Yi Lin Chiang, Dai Yu Chiu, U. Narasimha Rao

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)3 complex as the major product. Additions of the silyl anion to (η6-arene)Cr(CO)3 and (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes produce dienylsilanes after acid quenching.

Original languageEnglish
Pages (from-to)13-20
Number of pages8
JournalJournal of Organometallic Chemistry
Volume675
Issue number1-2
DOIs
Publication statusPublished - 2003 May 30

Fingerprint

Addition reactions
dienes
Carbon Monoxide
Quenching
quenching
trienes
Negative ions
anions
acids
Acids
products
Anions

Keywords

  • Arene
  • Chromium
  • Cyclohexadiene
  • Iron
  • Silane

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes. / Yeh, Ming-Chang P.; Sheu, Peng Yu; Ho, Jin Xuan; Chiang, Yi Lin; Chiu, Dai Yu; Narasimha Rao, U.

In: Journal of Organometallic Chemistry, Vol. 675, No. 1-2, 30.05.2003, p. 13-20.

Research output: Contribution to journalArticle

Yeh, Ming-Chang P. ; Sheu, Peng Yu ; Ho, Jin Xuan ; Chiang, Yi Lin ; Chiu, Dai Yu ; Narasimha Rao, U. / Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes. In: Journal of Organometallic Chemistry. 2003 ; Vol. 675, No. 1-2. pp. 13-20.
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abstract = "Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)3 complex as the major product. Additions of the silyl anion to (η6-arene)Cr(CO)3 and (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes produce dienylsilanes after acid quenching.",
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AU - Yeh, Ming-Chang P.

AU - Sheu, Peng Yu

AU - Ho, Jin Xuan

AU - Chiang, Yi Lin

AU - Chiu, Dai Yu

AU - Narasimha Rao, U.

PY - 2003/5/30

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AB - Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)3 complex as the major product. Additions of the silyl anion to (η6-arene)Cr(CO)3 and (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes produce dienylsilanes after acid quenching.

KW - Arene

KW - Chromium

KW - Cyclohexadiene

KW - Iron

KW - Silane

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