Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes

Ming Chang P. Yeh, Peng Yu Sheu, Jin Xuan Ho, Yi Lin Chiang, Dai Yu Chiu, U. Narasimha Rao

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4 Citations (Scopus)

Abstract

Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)3 complex as the major product. Additions of the silyl anion to (η6-arene)Cr(CO)3 and (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes produce dienylsilanes after acid quenching.

Original languageEnglish
Pages (from-to)13-20
Number of pages8
JournalJournal of Organometallic Chemistry
Volume675
Issue number1-2
DOIs
Publication statusPublished - 2003 May 30

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Keywords

  • Arene
  • Chromium
  • Cyclohexadiene
  • Iron
  • Silane

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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