A unique bismuth-iron chain polymer containing the ··· -Bi-Fe-··· link: Formation and structure of [nBuBiFe(CO)4]∞

Minghuey Shieh; Yeantarn Liou; Miao Hsing Hsu; Rung Tsang Chen; Shiow Jane Yeh; Shie Ming Peng; Gene Hsiang Lee

doi:10.1002/1521-3773(20020703)41:13<2384::aid-anie2384>3.0.co;2-%23

A unique bismuth-iron chain polymer containing the ··· -Bi-Fe-··· link: Formation and structure of [nBuBiFe(CO)₄]_∞

Minghuey Shieh^*, Yeantarn Liou, Miao Hsing Hsu, Rung Tsang Chen, Shiow Jane Yeh, Shie Ming Peng, Gene Hsiang Lee

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A unique zigzag ··· -Bi-Fe- ··· chain forms the basis of the structure of [nBuBiFe(CO)₄]_∞ (1; see picture), which was characterzized by single-crystal X-ray diffraction. Compound 1 was isolated from the ultrasonication of the dimeric product [{nBuBiFe(CO)₄}₂] from the reaction of [Et₄N]₃[Bi{Fe(CO)₄}₄] with nBuBr followed by acidification with HOAc.

Original language	English
Pages (from-to)	2384-2386
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	13
DOIs	https://doi.org/10.1002/1521-3773(20020703)41:13<2384::aid-anie2384>3.0.co;2-%23
Publication status	Published - 2002 Jul 2

Keywords

Bismuth
Carbonyl ligands
Iron
Metal-metal interactions
Polymers

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/1521-3773(20020703)41:13<2384::aid-anie2384>3.0.co;2-%23

Cite this

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title = "A unique bismuth-iron chain polymer containing the ··· -Bi-Fe-··· link: Formation and structure of [nBuBiFe(CO)4]∞",

abstract = "A unique zigzag ··· -Bi-Fe- ··· chain forms the basis of the structure of [nBuBiFe(CO)4]∞ (1; see picture), which was characterzized by single-crystal X-ray diffraction. Compound 1 was isolated from the ultrasonication of the dimeric product [{nBuBiFe(CO)4}2] from the reaction of [Et4N]3[Bi{Fe(CO)4}4] with nBuBr followed by acidification with HOAc.",

keywords = "Bismuth, Carbonyl ligands, Iron, Metal-metal interactions, Polymers",

author = "Minghuey Shieh and Yeantarn Liou and Hsu, {Miao Hsing} and Chen, {Rung Tsang} and Yeh, {Shiow Jane} and Peng, {Shie Ming} and Lee, {Gene Hsiang}",

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AU - Liou, Yeantarn

AU - Hsu, Miao Hsing

AU - Chen, Rung Tsang

AU - Yeh, Shiow Jane

AU - Peng, Shie Ming

AU - Lee, Gene Hsiang

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