Abstract
A unique zigzag ··· -Bi-Fe- ··· chain forms the basis of the structure of [nBuBiFe(CO)4]∞ (1; see picture), which was characterzized by single-crystal X-ray diffraction. Compound 1 was isolated from the ultrasonication of the dimeric product [{nBuBiFe(CO)4}2] from the reaction of [Et4N]3[Bi{Fe(CO)4}4] with nBuBr followed by acidification with HOAc.
Original language | English |
---|---|
Pages (from-to) | 2384-2386 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 41 |
Issue number | 13 |
DOIs | |
Publication status | Published - 2002 Jul 2 |
Keywords
- Bismuth
- Carbonyl ligands
- Iron
- Metal-metal interactions
- Polymers
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)