A unique bismuth-iron chain polymer containing the ··· -Bi-Fe-··· link: Formation and structure of [nBuBiFe(CO)4]

Minghuey Shieh, Yeantarn Liou, Miao Hsing Hsu, Rung Tsang Chen, Shiow Jane Yeh, Shie Ming Peng, Gene Hsiang Lee

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

A unique zigzag ··· -Bi-Fe- ··· chain forms the basis of the structure of [nBuBiFe(CO)4] (1; see picture), which was characterzized by single-crystal X-ray diffraction. Compound 1 was isolated from the ultrasonication of the dimeric product [{nBuBiFe(CO)4}2] from the reaction of [Et4N]3[Bi{Fe(CO)4}4] with nBuBr followed by acidification with HOAc.

Original languageEnglish
Pages (from-to)2384-2386
Number of pages3
JournalAngewandte Chemie - International Edition
Volume41
Issue number13
DOIs
Publication statusPublished - 2002 Jul 2

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Bismuth
Acidification
Carbon Monoxide
Polymers
Iron
Single crystals
X ray diffraction
X-Ray Diffraction

Keywords

  • Bismuth
  • Carbonyl ligands
  • Iron
  • Metal-metal interactions
  • Polymers

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

A unique bismuth-iron chain polymer containing the ··· -Bi-Fe-··· link : Formation and structure of [nBuBiFe(CO)4]. / Shieh, Minghuey; Liou, Yeantarn; Hsu, Miao Hsing; Chen, Rung Tsang; Yeh, Shiow Jane; Peng, Shie Ming; Lee, Gene Hsiang.

In: Angewandte Chemie - International Edition, Vol. 41, No. 13, 02.07.2002, p. 2384-2386.

Research output: Contribution to journalArticle

Shieh, Minghuey ; Liou, Yeantarn ; Hsu, Miao Hsing ; Chen, Rung Tsang ; Yeh, Shiow Jane ; Peng, Shie Ming ; Lee, Gene Hsiang. / A unique bismuth-iron chain polymer containing the ··· -Bi-Fe-··· link : Formation and structure of [nBuBiFe(CO)4]. In: Angewandte Chemie - International Edition. 2002 ; Vol. 41, No. 13. pp. 2384-2386.
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