A titanium(iii) phosphite exhibits polymorph-distinct redox activity involving proton-coupled electron transfer

Ling I. Hung, Tsung Hsiu Hsieh, Jhao Yang Syu, Pei Lin Chen, Chia Her Lin, Sue Lein Wang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A novel titanium(iii) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with subsequent photoreduction, the redox cycle initiated with TiIIIcan produce H2and transform organics.

Original languageEnglish
Pages (from-to)6542-6545
Number of pages4
JournalChemical Communications
Volume57
Issue number53
DOIs
Publication statusPublished - 2021 Jul 7

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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