A Stable Seven-Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle

Hemanta Kalita; Way Zen Lee; Gregory G. Theophall; K. V. Lakshmi; M. Ravikanth

doi:10.1002/chem.201501889

A Stable Seven-Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle

Hemanta Kalita, Way Zen Lee, Gregory G. Theophall, K. V. Lakshmi, M. Ravikanth^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Unprecedented examples of smaragdyrin macrocycles containing seven membered heterocyclic rings were synthesized under simple reaction conditions in high yields. The heterocycle formed inside smaragdyrin macrocycle is rare example of heterocycle containing five different atoms, such as B, C, N, O, and P atoms. The mixed B^III and P^V complexes of smaragdyrin macrocycles showed new structural, spectral, and electrochemical properties.

Original language	English
Pages (from-to)	11315-11319
Number of pages	5
Journal	Chemistry - A European Journal
Volume	21
Issue number	32
DOIs	https://doi.org/10.1002/chem.201501889
Publication status	Published - 2015 Aug 1

Keywords

absorption
fluorescence
heterocycles
macrocycles
smaragdyrin

ASJC Scopus subject areas

Catalysis
General Chemistry
Organic Chemistry

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10.1002/chem.201501889

Cite this

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title = "A Stable Seven-Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle",

abstract = "Unprecedented examples of smaragdyrin macrocycles containing seven membered heterocyclic rings were synthesized under simple reaction conditions in high yields. The heterocycle formed inside smaragdyrin macrocycle is rare example of heterocycle containing five different atoms, such as B, C, N, O, and P atoms. The mixed BIII and PV complexes of smaragdyrin macrocycles showed new structural, spectral, and electrochemical properties.",

keywords = "absorption, fluorescence, heterocycles, macrocycles, smaragdyrin",

author = "Hemanta Kalita and Lee, {Way Zen} and Theophall, {Gregory G.} and Lakshmi, {K. V.} and M. Ravikanth",

note = "Publisher Copyright: {\textcopyright} 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

year = "2015",

month = aug,

day = "1",

doi = "10.1002/chem.201501889",

language = "English",

volume = "21",

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journal = "Chemistry - A European Journal",

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publisher = "Wiley-VCH Verlag",

number = "32",

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TY - JOUR

T1 - A Stable Seven-Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle

AU - Kalita, Hemanta

AU - Lee, Way Zen

AU - Theophall, Gregory G.

AU - Lakshmi, K. V.

AU - Ravikanth, M.

PY - 2015/8/1

Y1 - 2015/8/1

N2 - Unprecedented examples of smaragdyrin macrocycles containing seven membered heterocyclic rings were synthesized under simple reaction conditions in high yields. The heterocycle formed inside smaragdyrin macrocycle is rare example of heterocycle containing five different atoms, such as B, C, N, O, and P atoms. The mixed BIII and PV complexes of smaragdyrin macrocycles showed new structural, spectral, and electrochemical properties.

AB - Unprecedented examples of smaragdyrin macrocycles containing seven membered heterocyclic rings were synthesized under simple reaction conditions in high yields. The heterocycle formed inside smaragdyrin macrocycle is rare example of heterocycle containing five different atoms, such as B, C, N, O, and P atoms. The mixed BIII and PV complexes of smaragdyrin macrocycles showed new structural, spectral, and electrochemical properties.

KW - absorption

KW - fluorescence

KW - heterocycles

KW - macrocycles

KW - smaragdyrin

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DO - 10.1002/chem.201501889

M3 - Article

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SN - 0947-6539

VL - 21

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EP - 11319

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 32

ER -

A Stable Seven-Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 1052162: Experimental Crystal Structure Determination

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A Stable Seven-Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1052162: Experimental Crystal Structure Determination

Cite this