A Stable Seven-Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle

Hemanta Kalita, Way-Zen Lee, Gregory G. Theophall, K. V. Lakshmi, M. Ravikanth

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Unprecedented examples of smaragdyrin macrocycles containing seven membered heterocyclic rings were synthesized under simple reaction conditions in high yields. The heterocycle formed inside smaragdyrin macrocycle is rare example of heterocycle containing five different atoms, such as B, C, N, O, and P atoms. The mixed BIII and PV complexes of smaragdyrin macrocycles showed new structural, spectral, and electrochemical properties.

Original languageEnglish
Pages (from-to)11315-11319
Number of pages5
JournalChemistry - A European Journal
Volume21
Issue number32
DOIs
Publication statusPublished - 2015 Aug 1

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Keywords

  • absorption
  • fluorescence
  • heterocycles
  • macrocycles
  • smaragdyrin

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Organic Chemistry

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