A Simple Approach to Enhance the Water Stability of a Metal-Organic Framework

Yung Han Shih; Yu Ching Kuo; Stephen Lirio; Kun Yun Wang; Chia Her Lin; Hsi Ya Huang

doi:10.1002/chem.201603647

A Simple Approach to Enhance the Water Stability of a Metal-Organic Framework

Yung Han Shih, Yu Ching Kuo, Stephen Lirio, Kun Yun Wang, Chia Her Lin, Hsi Ya Huang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

A facile method to improve the feasibility of water-unstable metal–organic frameworks in an aqueous environment has been developed that involves imbedding in a polymer monolith. The effect of compartment type during polymerization plays a significant role in maintaining the crystalline structure and thermal stability of the MOFs, which was confirmed by powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA), respectively. The MOF–polymer composite prepared in a narrow compartment (column, ID 0.8 mm) has better thermal and chemical stability than that prepared in a broad compartment (vial, ID 7 mm). The developed MOF–polymer composite was applied as an adsorbent in solid-phase microextraction of nine non-steroidal anti-inflammatory drugs (NSAIDs) and could be used for extraction more than 30 times, demonstrating that the proposed approach has potential for industrial applications.

Original language	English
Pages (from-to)	42-46
Number of pages	5
Journal	Chemistry - A European Journal
Volume	23
Issue number	1
DOIs	https://doi.org/10.1002/chem.201603647
Publication status	Published - 2017 Jan 1
Externally published	Yes

Keywords

MOF–polymer composites
metal–organic frameworks
polymer monoliths
stability

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.201603647

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abstract = "A facile method to improve the feasibility of water-unstable metal–organic frameworks in an aqueous environment has been developed that involves imbedding in a polymer monolith. The effect of compartment type during polymerization plays a significant role in maintaining the crystalline structure and thermal stability of the MOFs, which was confirmed by powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA), respectively. The MOF–polymer composite prepared in a narrow compartment (column, ID 0.8 mm) has better thermal and chemical stability than that prepared in a broad compartment (vial, ID 7 mm). The developed MOF–polymer composite was applied as an adsorbent in solid-phase microextraction of nine non-steroidal anti-inflammatory drugs (NSAIDs) and could be used for extraction more than 30 times, demonstrating that the proposed approach has potential for industrial applications.",

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AU - Lirio, Stephen

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AU - Lin, Chia Her

AU - Huang, Hsi Ya

PY - 2017/1/1

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N2 - A facile method to improve the feasibility of water-unstable metal–organic frameworks in an aqueous environment has been developed that involves imbedding in a polymer monolith. The effect of compartment type during polymerization plays a significant role in maintaining the crystalline structure and thermal stability of the MOFs, which was confirmed by powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA), respectively. The MOF–polymer composite prepared in a narrow compartment (column, ID 0.8 mm) has better thermal and chemical stability than that prepared in a broad compartment (vial, ID 7 mm). The developed MOF–polymer composite was applied as an adsorbent in solid-phase microextraction of nine non-steroidal anti-inflammatory drugs (NSAIDs) and could be used for extraction more than 30 times, demonstrating that the proposed approach has potential for industrial applications.

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A Simple Approach to Enhance the Water Stability of a Metal-Organic Framework

Abstract

Keywords

ASJC Scopus subject areas

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