A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

Chuan Hung Chuang; Malaichamy Sathiyendiran; Yi Hsiu Tseng; Jing Yun Wu; Kung Chung Hsu; Chen Hsiung Hung; Yuh Sheng Wen; Kuang Lieh Lu

doi:10.1021/om9007604

A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

Chuan Hung Chuang
, Malaichamy Sathiyendiran
, Yi Hsiu Tseng
, Jing Yun Wu
, Kung Chung Hsu
, Chen Hsiung Hung
, Yuh Sheng Wen
, Kuang Lieh Lu^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

Original language	English
Pages (from-to)	283-285
Number of pages	3
Journal	Organometallics
Volume	29
Issue number	2
DOIs	https://doi.org/10.1021/om9007604
Publication status	Published - 2010 Jan 25

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om9007604

Cite this

@article{2172bfacf8e1440e955a55610993cac7,

title = "A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand",

abstract = "Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.",

author = "Chuang, \{Chuan Hung\} and Malaichamy Sathiyendiran and Tseng, \{Yi Hsiu\} and Wu, \{Jing Yun\} and Hsu, \{Kung Chung\} and Hung, \{Chen Hsiung\} and Wen, \{Yuh Sheng\} and Lu, \{Kuang Lieh\}",

year = "2010",

month = jan,

day = "25",

doi = "10.1021/om9007604",

language = "English",

volume = "29",

pages = "283--285",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

AU - Chuang, Chuan Hung

AU - Sathiyendiran, Malaichamy

AU - Tseng, Yi Hsiu

AU - Wu, Jing Yun

AU - Hsu, Kung Chung

AU - Hung, Chen Hsiung

AU - Wen, Yuh Sheng

AU - Lu, Kuang Lieh

PY - 2010/1/25

Y1 - 2010/1/25

N2 - Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

AB - Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

UR - https://www.scopus.com/pages/publications/74549142872

UR - https://www.scopus.com/pages/publications/74549142872#tab=citedBy

U2 - 10.1021/om9007604

DO - 10.1021/om9007604

M3 - Article

AN - SCOPUS:74549142872

SN - 0276-7333

VL - 29

SP - 283

EP - 285

JO - Organometallics

JF - Organometallics

IS - 2

ER -

A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

CCDC 701808: Experimental Crystal Structure Determination

CCDC 808391: Experimental Crystal Structure Determination

Cite this

A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 701808: Experimental Crystal Structure Determination

CCDC 808391: Experimental Crystal Structure Determination

Cite this