Abstract
Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.
Original language | English |
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Pages (from-to) | 283-285 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 29 |
Issue number | 2 |
DOIs | |
Publication status | Published - 2010 Jan 25 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Dive into the research topics of 'A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand'. Together they form a unique fingerprint.Datasets
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CCDC 701808: Experimental Crystal Structure Determination
Chuang, C. (Creator), Sathiyendiran, M. (Contributor), Tseng, Y. (Creator), Wu, J. (Creator), Hsu, K. (Creator), Hung, C. (Creator), Wen, Y. (Creator) & Lu, K. (Creator), Unknown Publisher, 2011
DOI: 10.5517/ccrk8zj, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrk8zj&sid=DataCite
Dataset
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CCDC 808391: Experimental Crystal Structure Determination
Chuang, C. (Creator), Sathiyendiran, M. (Contributor), Tseng, Y. (Creator), Wu, J. (Creator), Hsu, K. (Creator), Hung, C. (Creator), Wen, Y. (Creator) & Lu, K. (Creator), Unknown Publisher, 2011
DOI: 10.5517/ccw464b, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw464b&sid=DataCite
Dataset