A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

Chuan Hung Chuang, Malaichamy Sathiyendiran, Yi Hsiu Tseng, Jing Yun Wu, Kung-Chung Hsu, Chen Hsiung Hung, Yuh Sheng Wen, Kuang Lieh Lu

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

Original languageEnglish
Pages (from-to)283-285
Number of pages3
JournalOrganometallics
Volume29
Issue number2
DOIs
Publication statusPublished - 2010 Jan 25

Fingerprint

rigidity
Rigidity
Ligands
ligands
Conformations
Self assembly
self assembly
modules
Modulation
modulation
preparation
predictions

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Chuang, C. H., Sathiyendiran, M., Tseng, Y. H., Wu, J. Y., Hsu, K-C., Hung, C. H., ... Lu, K. L. (2010). A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand. Organometallics, 29(2), 283-285. https://doi.org/10.1021/om9007604

A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand. / Chuang, Chuan Hung; Sathiyendiran, Malaichamy; Tseng, Yi Hsiu; Wu, Jing Yun; Hsu, Kung-Chung; Hung, Chen Hsiung; Wen, Yuh Sheng; Lu, Kuang Lieh.

In: Organometallics, Vol. 29, No. 2, 25.01.2010, p. 283-285.

Research output: Contribution to journalArticle

Chuang, CH, Sathiyendiran, M, Tseng, YH, Wu, JY, Hsu, K-C, Hung, CH, Wen, YS & Lu, KL 2010, 'A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand', Organometallics, vol. 29, no. 2, pp. 283-285. https://doi.org/10.1021/om9007604
Chuang, Chuan Hung ; Sathiyendiran, Malaichamy ; Tseng, Yi Hsiu ; Wu, Jing Yun ; Hsu, Kung-Chung ; Hung, Chen Hsiung ; Wen, Yuh Sheng ; Lu, Kuang Lieh. / A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand. In: Organometallics. 2010 ; Vol. 29, No. 2. pp. 283-285.
@article{f4ba98d313ee4d85b5acfd0019e1ef1c,
title = "A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand",
abstract = "Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.",
author = "Chuang, {Chuan Hung} and Malaichamy Sathiyendiran and Tseng, {Yi Hsiu} and Wu, {Jing Yun} and Kung-Chung Hsu and Hung, {Chen Hsiung} and Wen, {Yuh Sheng} and Lu, {Kuang Lieh}",
year = "2010",
month = "1",
day = "25",
doi = "10.1021/om9007604",
language = "English",
volume = "29",
pages = "283--285",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "2",

}

TY - JOUR

T1 - A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

AU - Chuang, Chuan Hung

AU - Sathiyendiran, Malaichamy

AU - Tseng, Yi Hsiu

AU - Wu, Jing Yun

AU - Hsu, Kung-Chung

AU - Hung, Chen Hsiung

AU - Wen, Yuh Sheng

AU - Lu, Kuang Lieh

PY - 2010/1/25

Y1 - 2010/1/25

N2 - Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

AB - Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

UR - http://www.scopus.com/inward/record.url?scp=74549142872&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=74549142872&partnerID=8YFLogxK

U2 - 10.1021/om9007604

DO - 10.1021/om9007604

M3 - Article

AN - SCOPUS:74549142872

VL - 29

SP - 283

EP - 285

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 2

ER -