A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

Chuan Hung Chuang; Malaichamy Sathiyendiran; Yi Hsiu Tseng; Jing Yun Wu; Kung-Chung Hsu; Chen Hsiung Hung; Yuh Sheng Wen; Kuang Lieh Lu

doi:10.1021/om9007604

A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

Chuan Hung Chuang, Malaichamy Sathiyendiran, Yi Hsiu Tseng, Jing Yun Wu, Kung-Chung Hsu, Chen Hsiung Hung, Yuh Sheng Wen, Kuang Lieh Lu

Department of Chemistry

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

Original language	English
Pages (from-to)	283-285
Number of pages	3
Journal	Organometallics
Volume	29
Issue number	2
DOIs	https://doi.org/10.1021/om9007604
Publication status	Published - 2010 Jan 25

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ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Cite this

Chuang, C. H., Sathiyendiran, M., Tseng, Y. H., Wu, J. Y., Hsu, K-C., Hung, C. H., Wen, Y. S., & Lu, K. L. (2010). A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand. Organometallics, 29(2), 283-285. https://doi.org/10.1021/om9007604

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AU - Wen, Yuh Sheng

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Access to Document

10.1021/om9007604