A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

Chuan Hung Chuang; Malaichamy Sathiyendiran; Yi Hsiu Tseng; Jing Yun Wu; Kung-Chung Hsu; Chen Hsiung Hung; Yuh Sheng Wen; Kuang Lieh Lu

doi:10.1021/om9007604

A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

Chuan Hung Chuang, Malaichamy Sathiyendiran, Yi Hsiu Tseng, Jing Yun Wu, Kung-Chung Hsu, Chen Hsiung Hung, Yuh Sheng Wen, Kuang Lieh Lu

Department of Chemistry

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

Original language	English
Pages (from-to)	283-285
Number of pages	3
Journal	Organometallics
Volume	29
Issue number	2
DOIs	https://doi.org/10.1021/om9007604
Publication status	Published - 2010 Jan 25

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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author = "Chuang, {Chuan Hung} and Malaichamy Sathiyendiran and Tseng, {Yi Hsiu} and Wu, {Jing Yun} and Kung-Chung Hsu and Hung, {Chen Hsiung} and Wen, {Yuh Sheng} and Lu, {Kuang Lieh}",

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AU - Chuang, Chuan Hung

AU - Sathiyendiran, Malaichamy

AU - Tseng, Yi Hsiu

AU - Wu, Jing Yun

AU - Hsu, Kung-Chung

AU - Hung, Chen Hsiung

AU - Wen, Yuh Sheng

AU - Lu, Kuang Lieh

PY - 2010/1/25

Y1 - 2010/1/25

N2 - Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

AB - Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

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