A novel interpenetrating diamondoid network from self-assembly of N,N′-di(4-pyridyl)adipoamide and copper sulfate: An unusual 12-fold, [6 + 6] mode

Yi Fen Hsu; Chia Her Lin; Jhy Der Chen; Ju Chun Wang

doi:10.1021/cg701209k

A novel interpenetrating diamondoid network from self-assembly of N,N′-di(4-pyridyl)adipoamide and copper sulfate: An unusual 12-fold, [6 + 6] mode

Yi Fen Hsu, Chia Her Lin, Jhy Der Chen^*, Ju Chun Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

115 Citations (Scopus)

Abstract

The polymeric complex [CuSO₄(L)(H₂O) ₂]∞ 1, which was prepared by the reaction of a flexible ligand N,N'-di(4-pyridyl)adipoamide), L, and copper sulfate forms a 12-fold diamondoid network showing an unusual [6 + 6] mode of interpenetration. The L ligands in 1 adopt the AAA trans and GAG trans conformations which also differ in the dihedral angle between the two pyridyl rings.

Original language	English
Pages (from-to)	1094-1096
Number of pages	3
Journal	Crystal Growth and Design
Volume	8
Issue number	4
DOIs	https://doi.org/10.1021/cg701209k
Publication status	Published - 2008 Apr
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "A novel interpenetrating diamondoid network from self-assembly of N,N′-di(4-pyridyl)adipoamide and copper sulfate: An unusual 12-fold, [6 + 6] mode",

abstract = "The polymeric complex [CuSO4(L)(H2O) 2]∞ 1, which was prepared by the reaction of a flexible ligand N,N'-di(4-pyridyl)adipoamide), L, and copper sulfate forms a 12-fold diamondoid network showing an unusual [6 + 6] mode of interpenetration. The L ligands in 1 adopt the AAA trans and GAG trans conformations which also differ in the dihedral angle between the two pyridyl rings.",

author = "Hsu, {Yi Fen} and Lin, {Chia Her} and Chen, {Jhy Der} and Wang, {Ju Chun}",

year = "2008",

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T2 - An unusual 12-fold, [6 + 6] mode

AU - Hsu, Yi Fen

AU - Lin, Chia Her

AU - Chen, Jhy Der

AU - Wang, Ju Chun

PY - 2008/4

Y1 - 2008/4

N2 - The polymeric complex [CuSO4(L)(H2O) 2]∞ 1, which was prepared by the reaction of a flexible ligand N,N'-di(4-pyridyl)adipoamide), L, and copper sulfate forms a 12-fold diamondoid network showing an unusual [6 + 6] mode of interpenetration. The L ligands in 1 adopt the AAA trans and GAG trans conformations which also differ in the dihedral angle between the two pyridyl rings.

AB - The polymeric complex [CuSO4(L)(H2O) 2]∞ 1, which was prepared by the reaction of a flexible ligand N,N'-di(4-pyridyl)adipoamide), L, and copper sulfate forms a 12-fold diamondoid network showing an unusual [6 + 6] mode of interpenetration. The L ligands in 1 adopt the AAA trans and GAG trans conformations which also differ in the dihedral angle between the two pyridyl rings.

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A novel interpenetrating diamondoid network from self-assembly of N,N′-di(4-pyridyl)adipoamide and copper sulfate: An unusual 12-fold, [6 + 6] mode

Abstract

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