A new hexanuclear manganese complex exhibits superparamagnetic behavior

Chen I. Yang; George Chung; Ting Shen Kuo; Minghuey Shieh; Hui Lien Tsai

doi:10.1246/cl.2006.724

A new hexanuclear manganese complex exhibits superparamagnetic behavior

Chen I. Yang, George Chung, Ting Shen Kuo, Minghuey Shieh, Hui Lien Tsai^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A new mixed-valence hexanuclear manganese(II,III) complex, [Mn ₆O₂(O₂CPh)₈(L)₃] (HL = 1-phenyl-3-pyridin-2-yl-propane-1,3-dione), has been synthesized and characterized structurally and magnetically. The complex contains a new [Mn ^II₃Mn^III₃O₂] ¹¹⁺ structural topology. The frequency dependence of out-of-phase component in alternating current magnetic susceptibilities for the complex indicates superparamagnetic behavior.

Original language	English
Pages (from-to)	724-725
Number of pages	2
Journal	Chemistry Letters
Volume	35
Issue number	7
DOIs	https://doi.org/10.1246/cl.2006.724
Publication status	Published - 2006 Jul 5

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2006.724

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@article{b238297b865f4b718e8c9f90a1f4b3d6,

title = "A new hexanuclear manganese complex exhibits superparamagnetic behavior",

abstract = "A new mixed-valence hexanuclear manganese(II,III) complex, [Mn 6O2(O2CPh)8(L)3] (HL = 1-phenyl-3-pyridin-2-yl-propane-1,3-dione), has been synthesized and characterized structurally and magnetically. The complex contains a new [Mn II3MnIII3O2] 11+ structural topology. The frequency dependence of out-of-phase component in alternating current magnetic susceptibilities for the complex indicates superparamagnetic behavior.",

author = "Yang, {Chen I.} and George Chung and Kuo, {Ting Shen} and Minghuey Shieh and Tsai, {Hui Lien}",

year = "2006",

month = jul,

day = "5",

doi = "10.1246/cl.2006.724",

language = "English",

volume = "35",

pages = "724--725",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "7",

}

TY - JOUR

T1 - A new hexanuclear manganese complex exhibits superparamagnetic behavior

AU - Yang, Chen I.

AU - Chung, George

AU - Kuo, Ting Shen

AU - Shieh, Minghuey

AU - Tsai, Hui Lien

PY - 2006/7/5

Y1 - 2006/7/5

N2 - A new mixed-valence hexanuclear manganese(II,III) complex, [Mn 6O2(O2CPh)8(L)3] (HL = 1-phenyl-3-pyridin-2-yl-propane-1,3-dione), has been synthesized and characterized structurally and magnetically. The complex contains a new [Mn II3MnIII3O2] 11+ structural topology. The frequency dependence of out-of-phase component in alternating current magnetic susceptibilities for the complex indicates superparamagnetic behavior.

AB - A new mixed-valence hexanuclear manganese(II,III) complex, [Mn 6O2(O2CPh)8(L)3] (HL = 1-phenyl-3-pyridin-2-yl-propane-1,3-dione), has been synthesized and characterized structurally and magnetically. The complex contains a new [Mn II3MnIII3O2] 11+ structural topology. The frequency dependence of out-of-phase component in alternating current magnetic susceptibilities for the complex indicates superparamagnetic behavior.

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DO - 10.1246/cl.2006.724

M3 - Article

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SP - 724

EP - 725

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 7

ER -

A new hexanuclear manganese complex exhibits superparamagnetic behavior

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CCDC 601063: Experimental Crystal Structure Determination

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A new hexanuclear manganese complex exhibits superparamagnetic behavior

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CCDC 601063: Experimental Crystal Structure Determination

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