A facile catalytic oxidation of activated hydrocarbons to the carbonyl functionality mediated by Mn(II) complexes

Jia Fu Pan; Kwunmin Chen

doi:10.1016/S1381-1169(01)00238-2

A facile catalytic oxidation of activated hydrocarbons to the carbonyl functionality mediated by Mn(II) complexes

Jia Fu Pan, Kwunmin Chen^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

Selective oxidation of activated hydrocarbons to the corresponding carbonyl functionality was achieved with good to high material yields using novel camphor-derived ligands mediated with Mn(II) as catalyst. In general, the reaction proceeds smoothly with 5 mol% of catalyst and 2.0 eq. of t-BuOOH as oxidant in CH₂Cl₂ in 5-30 min.

Original language	English
Pages (from-to)	19-22
Number of pages	4
Journal	Journal of Molecular Catalysis A: Chemical
Volume	176
Issue number	1-2
DOIs	https://doi.org/10.1016/S1381-1169(01)00238-2
Publication status	Published - 2001 Nov 20

Keywords

Catalyst
Chiral ligand
Enone
Hydrocarbon
Oxidation

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology
Physical and Theoretical Chemistry

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10.1016/S1381-1169(01)00238-2

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title = "A facile catalytic oxidation of activated hydrocarbons to the carbonyl functionality mediated by Mn(II) complexes",

abstract = "Selective oxidation of activated hydrocarbons to the corresponding carbonyl functionality was achieved with good to high material yields using novel camphor-derived ligands mediated with Mn(II) as catalyst. In general, the reaction proceeds smoothly with 5 mol% of catalyst and 2.0 eq. of t-BuOOH as oxidant in CH2Cl2 in 5-30 min.",

keywords = "Catalyst, Chiral ligand, Enone, Hydrocarbon, Oxidation",

author = "Pan, {Jia Fu} and Kwunmin Chen",

note = "Funding Information: Financial support by the National Science Council of the Republic of China and the collection and processing of the X-ray data for ligand 1 by the Taipei Instrumentation Center, College of Science (National Taiwan University), are gratefully acknowledged. ",

year = "2001",

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T1 - A facile catalytic oxidation of activated hydrocarbons to the carbonyl functionality mediated by Mn(II) complexes

AU - Pan, Jia Fu

AU - Chen, Kwunmin

N1 - Funding Information: Financial support by the National Science Council of the Republic of China and the collection and processing of the X-ray data for ligand 1 by the Taipei Instrumentation Center, College of Science (National Taiwan University), are gratefully acknowledged.

PY - 2001/11/20

Y1 - 2001/11/20

N2 - Selective oxidation of activated hydrocarbons to the corresponding carbonyl functionality was achieved with good to high material yields using novel camphor-derived ligands mediated with Mn(II) as catalyst. In general, the reaction proceeds smoothly with 5 mol% of catalyst and 2.0 eq. of t-BuOOH as oxidant in CH2Cl2 in 5-30 min.

AB - Selective oxidation of activated hydrocarbons to the corresponding carbonyl functionality was achieved with good to high material yields using novel camphor-derived ligands mediated with Mn(II) as catalyst. In general, the reaction proceeds smoothly with 5 mol% of catalyst and 2.0 eq. of t-BuOOH as oxidant in CH2Cl2 in 5-30 min.

KW - Catalyst

KW - Chiral ligand

KW - Enone

KW - Hydrocarbon

KW - Oxidation

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U2 - 10.1016/S1381-1169(01)00238-2

DO - 10.1016/S1381-1169(01)00238-2

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SN - 1381-1169

VL - 176

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EP - 22

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

A facile catalytic oxidation of activated hydrocarbons to the carbonyl functionality mediated by Mn(II) complexes

Abstract

Keywords

ASJC Scopus subject areas

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