A Cost-Effective, Nanoporous, High-Entropy Oxide Electrode for Electrocatalytic Water Splitting

Bu Jine Liu, Tai Hsin Yin, Yu Wei Lin, Chun Wei Chang, Hsin Chieh Yu, Yongtaek Lim, Hyesung Lee, Changsik Choi*, Ming Kang Tsai, Yong Man Choi*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

High-entropy materials have attracted extensive attention as emerging electrode materials in various energy applications due to their flexible tunability, unusual outstanding activities, and cost-effectiveness using multiple earth-abundant elements. We introduce a novel high-entropy composite oxide with the five elements of Cu, Ni, Co, Fe, and Cr (HEO-3CNF) for use in the oxygen evolution reaction (OER) in electrocatalytic water splitting. HEO-3CNF is composed of two phases with a non-equimolar, deficient high-entropy spinel oxide of (Cu0.2−xNi0.2Co0.2Fe0.2Cr0.2)3O4 and monoclinic copper oxide (CuO). Electrochemical impedance spectroscopy (EIS) with distribution of relaxation times (DRT) analysis validates that the HEO-3CNF-based electrode exhibits faster charge transfer than benchmark CuO. It results in improved OER performance with a lower overpotential at 10 mA/cm2 and a Tafel slope than CuO (518.1 mV and 119.7 mV/dec versus 615.9 mV and 131.7 mV/dec, respectively) in alkaline conditions. This work may provide a general strategy for preparing novel, cost-effective, high-entropy electrodes for water splitting.

Original languageEnglish
Article number1461
JournalCoatings
Volume13
Issue number8
DOIs
Publication statusPublished - 2023 Aug

Keywords

  • electrochemical impedance spectroscopy
  • high-entropy oxides
  • hydrogen production
  • thin films

ASJC Scopus subject areas

  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

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