[1,4-Bis(diphenylphosphanyl)butane-κ2P,P′] chlorido(η5-indenyl)ruthenium(II)

Hui Ling Sung; Tze Min Her; Wen Hsien Su; Chin Pao Cheng

doi:10.1107/S1600536811015121

[1,4-Bis(diphenylphosphanyl)butane-κ²P,P′] chlorido(η⁵-indenyl)ruthenium(II)

Hui Ling Sung^*, Tze Min Her, Wen Hsien Su, Chin Pao Cheng

^*Corresponding author for this work

Department of Mechatronic Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η⁵-C₉H₇)Cl(PPh₃) ₂] is treated with 1,4-bis(diphenylphosphanyl)butane in refluxing toluene yielding the title compound, [Ru(C₉H₇)Cl(C ₂₈H₂₈P₂)]. The Ru^II atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are 2.2502 (9) and 2.2968 (8) Å.

Original language	English
Pages (from-to)	m641
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	5
DOIs	https://doi.org/10.1107/S1600536811015121
Publication status	Published - 2011 May

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536811015121

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title = "[1,4-Bis(diphenylphosphanyl)butane-κ2P,P′] chlorido(η5-indenyl)ruthenium(II)",

abstract = "Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η5-C9H7)Cl(PPh3) 2] is treated with 1,4-bis(diphenylphosphanyl)butane in refluxing toluene yielding the title compound, [Ru(C9H7)Cl(C 28H28P2)]. The RuII atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are 2.2502 (9) and 2.2968 (8) {\AA}.",

author = "Sung, {Hui Ling} and Her, {Tze Min} and Su, {Wen Hsien} and Cheng, {Chin Pao}",

year = "2011",

month = may,

doi = "10.1107/S1600536811015121",

language = "English",

volume = "67",

pages = "m641",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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T1 - [1,4-Bis(diphenylphosphanyl)butane-κ2P,P′] chlorido(η5-indenyl)ruthenium(II)

AU - Sung, Hui Ling

AU - Her, Tze Min

AU - Su, Wen Hsien

AU - Cheng, Chin Pao

PY - 2011/5

Y1 - 2011/5

N2 - Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η5-C9H7)Cl(PPh3) 2] is treated with 1,4-bis(diphenylphosphanyl)butane in refluxing toluene yielding the title compound, [Ru(C9H7)Cl(C 28H28P2)]. The RuII atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are 2.2502 (9) and 2.2968 (8) Å.

AB - Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η5-C9H7)Cl(PPh3) 2] is treated with 1,4-bis(diphenylphosphanyl)butane in refluxing toluene yielding the title compound, [Ru(C9H7)Cl(C 28H28P2)]. The RuII atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are 2.2502 (9) and 2.2968 (8) Å.

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 5

ER -

[1,4-Bis(diphenylphosphanyl)butane-κ²P,P′] chlorido(η⁵-indenyl)ruthenium(II)

Abstract

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CCDC 825346: Experimental Crystal Structure Determination

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[1,4-Bis(diphenylphosphanyl)butane-κ2P,P′] chlorido(η5-indenyl)ruthenium(II)

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 825346: Experimental Crystal Structure Determination

Cite this

[1,4-Bis(diphenylphosphanyl)butane-κ²P,P′] chlorido(η⁵-indenyl)ruthenium(II)