[1,4-Bis(diphenylphosphanyl)butane-κ2P,P′] chlorido(η5-indenyl)ruthenium(II)

Hui Ling Sung, Tze Min Her, Wen Hsien Su, Chin Pao Cheng

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η5-C9H7)Cl(PPh3) 2] is treated with 1,4-bis(diphenylphosphanyl)butane in refluxing toluene yielding the title compound, [Ru(C9H7)Cl(C 28H28P2)]. The RuII atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are 2.2502 (9) and 2.2968 (8) Å.

Original languageEnglish
Pages (from-to)m641
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number5
DOIs
Publication statusPublished - 2011 May 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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