1,3-Diphenyl-2-tricyclo[3.3.1.1 3,7]dec-2-ylidenepropane-l,3-diimine, and its -1-imino-3-one and -1,3-dione derivatives

Ching Fa Yao, Yuh Shih Chen, Wen Chang Chen, Ren Shyang Sheu, Jen Kou Lai, Chuen Her Ueng

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

1,3-Diphenyl-2-tricyclo[3.3.1.1 3,7]dec-2-ylidenepropane-1,3-diimine, C25H26N2, (1), 1-imino-1,3-diphenyl-2-tricyclo[3.3.1.13,7]dec-2-ylidenepropan-3-one, C25H25NO, (2) and 1,3-diphenyl-2-tricyclo[3.3.1.13,7]dec-2-ylidenepropane-1,3-dione, C25H24O2, (3), were prepared from the reactions of 2-(dicyanomethylene)adamantane with phenylmagnesium bromide upon workup with dry methanol or dilute acid aqueous solution, and their crystal structures were determined by X-ray diffraction. Compounds (1) and (2) have similar molecular structures with the two imino groups in (1) and the imino and ketone groups in (2) being on the same side of the C1, C2, C12, C13 plane, compared with the two O atoms in compound (3), which are on opposite sides.

Original languageEnglish
Pages (from-to)956-959
Number of pages4
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume53
Issue number7
DOIs
Publication statusPublished - 1997 Jul 15

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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